The History of Chemistry, Volume 1 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 1 (of 2)
Thomson, Thomas
Chemistry -- History
1. Twelve ounces of Japan copper were beat into thin plates, and laid
_stratum super stratum_ with three ounces of flowers of sulphur, in a
crucible. It was exposed in a melting-furnace to a gentle heat, till
the sulphureous flames expired. When cold, the æs ustum (_sulphuret
of copper_) was pounded, and stratified again; and this process was
repeated five times. Mr. Wilson does not inform us whether the powder
was mixed with flowers of sulphur every time that it was heated; but
this must have been the case, otherwise the sulphuret would have been
again converted into metallic copper, which would have melted into a
mass. By this first process, then, bisulphuret of copper was formed,
composed of equal weights of sulphur and copper.
2. Six pounds of iron wire were put into a large glass body, and twelve
pounds of muriatic acid poured upon it. Six days elapsed (during which
it stood in a gentle heat) before the acid was saturated with the iron.
The solution was then decanted off, and filtered, and six pounds of new
muriatic acid poured on the undissolved iron. This acid, after standing
a sufficient time, was decanted off, and filtered. Both liquids were
put into a large retort, and distilled by a sand-heat. Towards the
end, when the drops from the retort became yellow, the receiver was
changed, and the fire increased to the highest degree, in which the
retort was kept between four and six hours. When all was cold, the
receiver was taken off, and a quantity of flowers was found in the neck
of the retort, variously coloured, like the rainbow. The yellow liquor
in the receiver weighed ten ounces and a half; the flowers (_chloride
of iron_), two ounces and three drams. The liquid and flowers were put
into a clean bottle.
3. Half a pound of sal enixum (_sulphate of potash_) and a pound and a
half of nitric acid were put into a retort. When the salt had dissolved
in the acid, ten ounces of mercury (previously distilled through
quicklime and salt of tartar) were added. The whole being distilled to
dryness, a fine yellow mass (_pernitrate of mercury_) remained in the
bottom of the retort. The liquor was returned, with half a pound of
fresh nitric acid, and the distillation repeated. The distillation was
repeated a third time, urging this last cohobation with the highest
degree of fire. When all was cold, a various-coloured mass was found in
the bottom of the retort: this mass was doubtless a mixture of sulphate
of potash, and pernitrate of mercury, with some oxide of mercury.
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