The History of Chemistry, Volume 1 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 1 (of 2)
Thomson, Thomas
Chemistry -- History
4. Four ounces of fine silver were dissolved in a pound of aqua fortis;
to the solution was added, of the bisulphuret of copper four ounces;
of the mixture of sulphate of potash, pernitrate of mercury, and oxide
of mercury one ounce and a half, and of the solution of perchloride
of iron two ounces and a half. When these had stood in a retort
twenty-four hours, the liquor was decanted off, and four ounces of
nitric acid were poured upon the little matter that was not dissolved.
Next morning a total dissolution was obtained. The whole of this
dissolution was put into a retort and distilled almost to dryness. The
liquid was poured back, and the distillation repeated three times; the
last time the retort being urged by a very strong fire till no fumes
appeared, and not a drop fell.
5. The matter left in the bottom of the retort was now put into a
crucible, all the corrosive fumes were gently evaporated, and the
residue melted down with a fluxing powder.
This process was expected to yield five ounces of pure gold; but
on examination the silver was the same (except the loss of half a
pennyweight) as when dissolved in the aqua fortis: there were indeed
some grains among the scoria, which appeared like gold, and would not
dissolve in aqua fortis. No doubt they consisted of peroxide of iron,
or, perhaps, persulphuret of iron.[15]
[15] Wilson’s Chemistry, p. 375.
Mr. Wilson’s alchymistical friend, not satisfied with this first
failure, insisted upon a repetition of the process, with some
alteration in the method and the addition of a certain quantity
of gold. The whole was accordingly gone through again; but it is
unnecessary to say that no gold was obtained, or at least, the two
drams of gold employed had increased in weight by only two scruples and
thirteen grains; this addition was doubtless owing to a little silver
from which it had not been freed.[16]
[16] Ibid., p. 379.
I shall now give a process for making the philosopher’s stone, which
was considered by Mangetus as of great value, and on that account was
given by him in the preface to his Bibliotheca Chemica.
1. Prepare a quantity of spirit of wine, so free from water that it is
wholly combustible, and so volatile that when a drop of it is let fall
it evaporates before it reaches the ground;--this constitutes the first
menstruum.
2. Take pure mercury, revived in the usual manner from cinnabar, put
it into a glass vessel with common salt and distilled vinegar; agitate
violently, and when the vinegar acquires a black colour pour it off and
add new vinegar; agitate again, and continue these repeated agitations
and additions till the vinegar ceases to acquire a black colour from
the mercury: the mercury is now quite pure and very brilliant.
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