The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
Such is a short view of the most material facts for which chemistry
is indebted to Dr. Priestley. As a discoverer of new substances, his
name must always stand very high in the science; but as a reasoner or
theorist his position will not be so favourable. It will be observed
that almost all his researches and discoveries related to gaseous
bodies. He determined the different processes, by means of which the
different gases can be procured, the substances which yield them, and
the effects which they are capable of producing on other bodies. Of
the other departments of chemistry he could hardly be said to know any
thing. As a pneumatic chemist he stands high; as an analytical chemist
he can scarcely claim any rank whatever. In his famous experiments on
the formation of water by detonating mixtures of oxygen and hydrogen
in a copper globe, the copper was found acted upon, and a blue liquid
was obtained, the nature of which he was unable to ascertain; but Mr.
Keir, whose assistance he solicited, determined it to be a solution of
nitrate of copper in water. This formation of nitric acid induced him
to deny that water was a compound of oxygen and hydrogen. The same acid
was formed in the experiments of Mr. Cavendish; but he investigated
the circumstances of the formation, and showed that it depended upon
the presence of azotic gas in the gaseous mixture. Whenever azotic
gas is present, nitric acid is formed, and the quantity of this acid
depends upon the relative proportion of the azotic and hydrogen gases
in the mixture. When no hydrogen gas is present, nothing is formed
but nitric acid: when no azotic gas is present, nothing is formed
but water. These facts, determined by Cavendish, invalidate the
reasoning of Priestley altogether; and had he possessed the skill, like
Cavendish, to determine with sufficient accuracy the proportions of the
different gases in his mixtures, and the relative quantities of nitric
acid formed, he would have seen the inaccuracy of his own conclusions.
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