The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
He was a firm believer in the existence of phlogiston; but he seems,
at least ultimately, to have adopted the view of Scheele, and many
other eminent contemporary chemists--indeed, the view of Cavendish
himself--that hydrogen gas is phlogiston in a separate and pure state.
Common air he considered as a compound of oxygen and phlogiston.
Oxygen, in his opinion, was air quite free from phlogiston, or air in
a simple and pure state; while _azotic gas_ (the other constituent of
common air) was air saturated with phlogiston. Hence he called oxygen
_dephlogisticated_, and azote _phlogisticated air_. The facts that
when common air is converted into azotic gas its bulk is diminished
about one-fifth part, and that azotic gas is lighter than common air or
oxygen gas, though not quite unknown to him, do not seem to have drawn
much of his attention. He was not accustomed to use a balance in his
experiments, nor to attend much to the alterations which took place in
the weight of bodies. Had he done so, most of his theoretical opinions
would have fallen to the ground.
When a body is allowed to burn in a given quantity of common air, it is
known that the quality of the common air is deteriorated; it becomes,
in his language, more phlogisticated. This, in his opinion, was owing
to an affinity which existed between phlogiston and air. The presence
of air is necessary to combustion, in consequence of the affinity which
it has for phlogiston. It draws phlogiston out of the burning body,
in order to combine with it. When a given bulk of air is saturated
with phlogiston, it is converted into azotic gas, or _phlogisticated
air_, as he called it; and this air, having no longer any affinity for
phlogiston, can no longer attract that principle, and consequently
combustion cannot go on in such air.
All combustible bodies, in his opinion, contain hydrogen. Of course
the metals contain it as a constituent. The calces of metals are those
bodies deprived of phlogiston. To prove the truth of this opinion, he
showed that when the oxide of iron is heated in hydrogen gas, that gas
is absorbed, while the calx is reduced to the metallic state. Finery
cinder, which he employed in these experiments, is, in his opinion,
iron not quite free from phlogiston. Hence it still retains a quantity
of hydrogen. To prove this, he mixed together finery cinder and
carbonates of lime, barytes and strontian, and exposed the mixture to a
strong heat; and by this process obtained inflammable gas in abundance.
In his opinion every inflammable gas contains hydrogen in abundance.
Hence this experiment was adduced by him as a demonstration that
hydrogen is a constituent of finery cinder.
Public-domain text, read in full here on John Shaqi.
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