The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
10. Bergman's experiments on the precious stones constitute the first
rudiments of the method of analyzing stony bodies. His processes are
very imperfect, and his apparatus but ill adapted to the purpose. We
need not be surprised, therefore, that the results of his analyses
are extremely wide of the truth. Yet, if we study his processes, we
shall find in them the rudiments of the very methods which we follow
at present. The superiority of the modern analyses over those of
Bergman must in a great measure be ascribed to the platinum vessels
which we now employ, and to the superior purity of the substances which
we use as reagents in our analyses. The methods, too, are simplified
and perfected. But we must not forget that this paper of Bergman's,
imperfect as it is, constitutes the commencement of the art, and that
fully as much genius and invention may be requisite to contrive the
first rude processes, how imperfect soever they may be, as are required
to bring these processes when once invented to a state of comparative
perfection. The great step in analyzing minerals is to render them
soluble in acids. Bergman first thought of the method for accomplishing
this which is still followed, namely, fusing them or heating them to
redness with an alkali or alkaline carbonate.
11. The paper on fulminating gold goes a great way to explain the
nature of that curious compound. He describes the properties of this
substance, and the effects of alkaline and acid bodies on it. He
shows that it cannot be formed without ammonia, and infers from his
experiments that it is a compound of oxide of gold and ammonia. He
explains the fulmination by the elastic fluid suddenly generated by the
decomposition of the ammonia.
12. The papers on platinum, carbonate of iron, nickel, arsenic, and
zinc, do not require many remarks. They add considerably to the
knowledge which chemists at that time possessed of these bodies; though
the modes of analysis are not such as would be approved of by a modern
chemist; nor were the results obtained possessed of much precision.
13. The Essay on the Analysis of Metallic Ores by the wet way, or by
solution, constitutes the first attempt to establish a regular method
of analyzing metallic ores. The processes are all imperfect, as might
be expected from the then existing state of analytical chemistry, and
the imperfect knowledge possessed, of the different metallic ores.
But this essay constituted a first beginning, for which the author is
entitled to great praise. The subject was taken up by Klaproth, and
speedily brought to a great degree of improvement by the labours of
modern chemists.
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