The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
14. The experiments on the way in which minerals behave before the
blowpipe, which Bergman published, were made at Bergman's request
by Assessor Gahn, of Fahlun, who was then his pupil. They constitute
the first results obtained by that very ingenious and amiable man. He
afterwards continued the investigation, and added many improvements,
simplifying the reagents and the manner of using them. But he was too
indolent a man to commit the results of his investigations to writing.
Berzelius, however, had the good sense to see the importance of the
facts which Gahn had ascertained. He committed them to writing, and
published them for the use of mineralogists. They constitute the book
entitled "Berzelius on the Blowpipe," which has been translated into
English.
15. The object of the Essay on Metallic Precipitates is to determine
the quantity of phlogiston which each metal contains, deduced from
the quantity of one metal necessary to precipitate a given weight of
another. The experiments are obviously made with little accuracy:
indeed they are not susceptible of very great precision. Lavoisier
afterwards made use of the same method to determine the quantity of
oxygen in the different metallic oxides; but his results were not more
successful than those of Bergman.
16. Bergman's paper on iron is one of the most important in his whole
works, and contributed very materially to advance the knowledge of
the cause of the difference between iron and steel. He employed
his pupils to collect specimens of iron from the different Swedish
forges, and gave them directions how to select the proper pieces.
All these specimens, to the number of eighty-nine, he subjected to a
chemical examination, by dissolving them in dilute sulphuric acid. He
measured the volume of hydrogen gas, which he obtained by dissolving
a given weight of each, and noted the quantity and the nature of the
undissolved residue. The general result of the whole investigation
was that pure malleable iron yielded most hydrogen gas; steel less,
and cast-iron least of all. Pure malleable iron left the smallest
quantity of insoluble matter, steel a greater quantity, and cast-iron
the greatest of all. From these experiments he drew conclusions with
respect to the difference between iron, steel, and cast-iron. Nothing
more was necessary than to apply the antiphlogistic theory to these
experiments, (as was done soon after by the French chemists,) in
order to draw important conclusions respecting the nature of these
bodies. Iron is a simple body; steel is a compound of iron and carbon;
and cast-iron of iron and a still greater proportion of carbon. The
defective part of the experiments of Bergman in this important paper
is his method of determining the quantity of _manganese_ in iron. In
some specimens he makes the manganese amount to considerably more than
a third part of the weight of the whole. Now we know that a mixture of
two parts iron and one part manganese is brittle and useless. We are
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