The History of Chemistry, Volume 2 (of 2) — John Shaqi
The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
In 1765 Scheele went to Malmo, to the house of an apothecary, called
Mr. Kalstrom. After spending two years in that place, he went to
Stockholm, to superintend the apothecary's shop of Mr. Scharenberg. In
1773 he exchanged this situation for another at Upsala, in the house of
Mr. Loock. It was here that he accidentally formed an acquaintance with
Assessor Gahn, of Fahlun, who was at that time a student at Upsala, and
a zealous chemist. Mr. Gahn happening to be one day in the shop of Mr.
Loock, that gentleman mentioned to him a circumstance which had lately
occurred to him, and of which he was anxious to obtain an explanation.
If a quantity of saltpetre be put into a crucible and raised to such a
temperature as shall not merely melt it, but occasion an agitation in
it like boiling, and if, after a certain time, the crucible be taken
out of the fire and allowed to cool, the saltpetre still continues
neutral; but its properties are altered: for, if distilled vinegar be
poured upon it, red fumes are given out, while vinegar produces no
effect upon the saltpetre before it has been thus heated. Mr. Loock
wished from Gahn an explanation of the cause of this phenomenon: Gahn
was unable to explain it; but promised to put the question to Professor
Bergman. He did so accordingly, but Bergman was as unable to find an
explanation as himself. On returning a few days after to Mr. Loock's
shop, Gahn was informed that there was a young man in the shop who had
given an explanation of the phenomenon. This young man was Scheele, who
had informed Mr. Loock that there were two species of acids confounded
under the name of _spirit of nitre_; what we at present call _nitric_
and _hyponitrous_ acids. Nitric acid has a stronger affinity for potash
than vinegar has; but hyponitrous acid has a weaker. The heat of the
fire changes the _nitric_ acid of the saltpetre to _hyponitrous_: hence
the phenomenon.
Gahn was delighted with the information, and immediately formed an
acquaintance with Scheele, which soon ripened into friendship. When he
informed Bergman of Scheele's explanation, the professor was equally
delighted, and expressed an eager desire to be made acquainted with
Scheele; but when Gahn mentioned the circumstance to Scheele, and
offered to introduce him to Bergman, our young chemist rejected the
proposal with strong feelings of dislike.
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