The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
This explanation was so simple and appeared so satisfactory, that it
was universally adopted by chemists with the exception of Lavoisier
himself. There was a circumstance, however, which satisfied him that
this explanation, however plausible, was not correct. The calx was
_heavier_ than the metal from which it had been produced. And hydrogen,
though a light body, was still possessed of weight. It was obviously
impossible, then, that the metal could be a combination of the calx and
hydrogen. Besides, he had ascertained by direct experiment, that the
calces of mercury, tin, and lead are compounds of the respective metals
and oxygen. And it was known that when the other calces were heated
with charcoal, they were reduced to the metallic state, and at the same
time carbonic acid gas is evolved. The very same evolution takes place
when calces of mercury, tin, and lead, are heated with charcoal powder.
Hence the inference was obvious that carbonic acid is a compound of
charcoal and oxygen, and therefore that all calces are compounds of
their respective metals and oxygen.
Thus, although Lavoisier was unable to account for the phenomena
connected with the evolution and absorption of hydrogen gas, he had
conclusive evidence that the orthodox explanation was not the true one.
He wisely, therefore, left it to time to throw light upon those parts
of the theory that were still obscure.
His next paper, which was likewise inserted in the Memoirs of the
Academy, for 1777, had some tendency to throw light on this subject,
or at least it elucidated the constitution of sulphuric acid, which
bore directly upon the antiphlogistic theory. It was entitled, "On the
Solution of Mercury in vitriolic Acid, and on the Resolution of that
Acid into aeriform sulphurous Acid, and into Air eminently Respirable."
Public-domain text, read in full here on John Shaqi.
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