The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
There appeared likewise another paper by Lavoisier, in the same volume
of the academy, which may be mentioned, as it served still further to
demonstrate the truth of the antiphlogistic theory. It is entitled, "On
the Vitriolization of Martial Pyrites." Iron pyrites is known to be a
compound of _iron_ and _sulphur_. Sometimes this mineral may be left
exposed to the air without undergoing any alteration, while at other
times it speedily splits, effloresces, swells, and is converted into
sulphate of iron. There are two species of pyrites; the one composed
of two atoms of sulphur and one atom of iron, the other of one atom of
sulphur and one atom of iron. The first of these is called bisulphuret
of iron; the second protosulphuret, or simply sulphuret of iron. The
variety of pyrites which undergoes spontaneous decomposition in the
air, is known to be a compound, or rather mixture of the two species of
pyrites.
Lavoisier put a quantity of the decomposing pyrites under a glass jar,
and found that the process went on just as well as in the open air.
He found that the air was deprived of the whole of its oxygen by the
process, and that nothing was left but azotic gas. Hence the nature
of the change became evident. The sulphur, by uniting with oxygen,
was converted into sulphuric acid, while the iron became oxide of
iron, and both uniting, formed sulphate of iron. There are still some
difficulties connected with this change that require to be elucidated.
We have still another paper by Lavoisier, bearing on the antiphlogistic
theory, published in the same volume of the Memoirs of the Academy,
for 1778, entitled, "On Combustion in general." He establishes that
the only air capable of supporting combustion is oxygen gas: that
during the burning of bodies in common air, a portion of the oxygen of
the atmosphere disappears, and unites with the burning body, and that
the new compound formed is either an acid or a metallic calx. When
sulphur is burnt, sulphuric acid is formed; when phosphorus, phosphoric
acid; and when charcoal, carbonic acid. The calcination of metals is
a process analogous to combustion, differing chiefly by the slowness
of the process: indeed when it takes place rapidly, actual combustion
is produced. After establishing these general principles, which are
deduced from his preceding papers, he proceeds to examine the Stahlian
theory of phlogiston, and shows that no evidence of the existence of
any such principle can be adduced, and that the phenomena can all be
explained without having recourse to it. Powerful as these arguments
were, they produced no immediate effects. Nobody chose to give up the
phlogistic theory to which he had been so long accustomed.
The next two papers of Lavoisier require merely to be mentioned, as
they do not bear immediately upon the antiphlogistic theory. They
appeared in the Memoirs of the Academy, for 1780. These memoirs were,
1. Second Memoir on the different Combinations of Phosphoric Acid.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account