The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
2. On a particular Process, by means of which Phosphorus may be
converted into phosphoric Acid, without Combustion.
The process here described consisted in throwing phosphorus, by a
few grains at a time, into warm nitric acid of the specific gravity
1·29895. It falls to the bottom like melted wax, and dissolves pretty
rapidly with effervescence: then another portion is thrown in, and the
process is continued till as much phosphorus has been employed as is
wanted; then the phosphoric acid may be obtained pure by distilling off
the remaining nitric acid with which it is still mixed.
Hitherto Lavoisier had been unable to explain the anomalies respecting
hydrogen gas, or to answer the objections urged against his theory
in consequence of these anomalies. He had made several attempts to
discover what peculiar substance was formed during the combustion of
hydrogen, but always without success: at last, in 1783, he resolved to
make the experiment upon so large a scale, that whatever the product
might be, it should not escape him; but Sir Charles Blagden, who
had just gone to Paris, informed him that the experiment for which
he was preparing had already been made by Mr. Cavendish, who had
ascertained that the product of the combustion of hydrogen was _water_.
Lavoisier saw at a glance the vast importance of this discovery for
the establishment of the antiphlogistic theory, and with what ease it
would enable him to answer all the plausible objections which had been
brought forward against his opinions in consequence of the evolution
of hydrogen, when metals were calcined by solution in acids, and the
absorption of it when metals were reduced in an atmosphere of this
gas. He therefore resolved to repeat the experiment of Cavendish with
every possible care, and upon a scale sufficiently large to prevent
ambiguity. The experiment was made on the 24th of June, 1783, by
Lavoisier and Laplace, in the presence of M. Le Roi, M. Vandermonde,
and Sir Charles Blagden, who was at that time secretary of the Royal
Society. The quantity of water formed was considerable, and they found
that water was a compound of
1 volume oxygen
1·91 volume hydrogen.
Not satisfied with this, he soon after made another experiment along
with M. Meusnier to decompose water. For this purpose a porcelain tube,
filled with iron wire, was heated red-hot by being passed through a
furnace, and then the steam of water was made to traverse the red-hot
wire. To the further extremity of the porcelain tube a glass tube was
luted, which terminated in a water-trough under an inverted glass
receiver placed to collect the gas. The steam was decomposed by the
red-hot iron wire, its oxygen united to the wire, while the hydrogen
passed on and was collected in the water-cistern.
Both of these experiments, though not made till 1783, and though the
latter of them was not read to the academy till 1784, were published in
the volume of the Memoirs for 1781.
Public-domain text, read in full here on John Shaqi.
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