The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
It is easy to see how this important discovery enabled Lavoisier to
obviate all the objections to his theory from hydrogen. He showed that
it was evolved when zinc or iron was dissolved in dilute sulphuric
acid, because the water underwent decomposition, its oxygen uniting to
the zinc or iron, and converting it into an oxide, while its hydrogen
made its escape in the state of gas. Oxide of iron was reduced when
heated in contact with hydrogen gas, because the hydrogen united to
the oxygen of the acid and formed water, and of course the iron was
reduced to the state of a metal. I consider it unnecessary to enter
into a minute detail of these experiments, because, in fact, they
added very little to what had been already established by Cavendish.
But it was this discovery that contributed more than any thing else
to establish the antiphlogistic theory. Accordingly, the great object
of Dr. Priestley, and other advocates of the phlogistic theory, was
to disprove the fact that water is a compound of oxygen and hydrogen.
Scheele admitted the fact that water is a compound of oxygen and
hydrogen; and doubtless, had he lived, would have become a convert
to the antiphlogistic theory, as Dr. Black actually did. In short,
it was the discovery of the compound nature of water that gave the
Lavoisierian theory the superiority over that of Stahl. Till the time
of this discovery every body opposed the doctrine of Lavoisier; but
within a very few years after it, hardly any supporters of phlogiston
remained. Nothing could be more fortunate for Lavoisier than this
discovery, or afford him greater reason for self-congratulation.
We see the effect of this discovery upon his next paper, "On the
Formation of Carbonic Acid," which appeared in the Memoirs of the
Academy, for 1781. There, for the first time, he introduces new terms,
showing, by that, that he considered his opinions as fully established.
To the _dephlogisticated air_ of Priestley, or his own _pure air_, he
now gives the name of _oxygen_. The fixed air of Black he designates
_carbonic acid_, because he considered it as a compound of _carbon_
(the pure part of charcoal) and oxygen. The object of this paper is to
determine the proportion of the constituents. He details a great many
experiments, and deduces from them all, that carbonic acid gas is a
compound of
Carbon 0·75
Oxygen 1·93
Now this is a tolerably near approximation to the truth. The true
constituents, as determined by modern chemists, being
Carbon 0·75
Oxygen 2·00
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