The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
which the vegetable body contains. The oil, the acid, &c., extracted
by distilling vegetable bodies did not exist in them, but are formed
during the mutual action of the constituents upon each other,
promoted as their action is by the heat. These views were quite new
and perfectly just, and threw a new light on the nature of vegetable
substances and on the products obtained by distilling them. It showed
the futility of all the pretended analyses of vegetable substances,
which chemists had performed by simply subjecting them to distillation,
and the error of drawing any conclusions respecting the constituents
of vegetable substances from the results of their distillation, except
indeed with respect to their elementary constituents. Thus when by
distilling a vegetable substance we obtain water, oil, acetic acid,
carbonic acid, and carburetted hydrogen, we must not conclude that
these principles existed in the substance, but merely that it contained
carbon, hydrogen, and oxygen, in such proportions as to yield all these
principles by decompositions.
As nitric acid acts upon metals in a very different way from sulphuric
and muriatic acids, and as it is a much better solvent of metals in
general than any other, it was an object of great importance towards
completing the antiphlogistic theory to obtain an accurate knowledge
of its constituents. Though Lavoisier did not succeed in this, yet he
made at least a certain progress, which enabled him to explain the
phenomena, at that time known, with considerable clearness, and to
answer all the objections to the antiphlogistic theory from the action
of nitric acid on metals. His first paper on the subject was published
in the Memoirs of the Academy, for 1776. He put a quantity of nitric
acid and mercury into a retort with a long beak, which he plunged into
the water-trough. An effervescence took place and gas passed over
in abundance, and was collected in a glass jar; the mercury being
dissolved the retort was still further heated, till every thing liquid
passed over into the receiver, and a dry yellow salt remained. The beak
of the retort was now again plunged into the water-trough, and the salt
heated till all the nitric acid which it contained was decomposed,
and nothing remained in the retort but red oxide of mercury. During
this last process much more gas was collected. All the gas obtained
during the solution of the mercury and the decomposition of the salt
was nitrous gas. The red oxide of mercury was now heated to redness,
oxygen gas was emitted in abundance, and the mercury was reduced to the
metallic state: its weight was found the very same as at first. It is
clear, therefore, that the nitrous gas and the oxygen gas were derived,
not from the mercury but from the nitric acid, and that the nitric acid
had been decomposed into nitrous gas and oxygen: the nitrous gas had
made its escape in the form of gas, and the oxygen had remained united
to the metal.
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