The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)Paris, John Ayrton
History
The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
A very general belief prevailed, that sea-water had little or no
action on _pure_ copper, and that the rapid decay of that metal on
certain ships was owing to its impurity. On submitting, however,
various specimens of copper to the action of the sea-water, Sir
H. Davy came to a conclusion, in direct opposition to such an
opinion;[91] and Mr. Knowles informed me, in a late conversation
upon the subject, that the attempts to purify the metal, since the
Government has manufactured its own copper sheathing, has been the
cause of its more rapid decay. It will however presently appear,
that the relative durability of the metallic sheets must also be
influenced by circumstances wholly independent of their quality,
some of which are very probably, even in our present advanced state
of chemical knowledge, not thoroughly understood.
[91] In two instances, the copper (from the Batavier and from
the Plymouth yacht) which had remained perfect for twenty-seven
years, was found to be alloyed. In the former one there was an
alloy of one three-hundredth part of zinc; and, in the latter,
the same proportion of tin. On the other hand, in the case of
the copper on the Tartar's bottom, which was nearly destroyed in
four years, upon being submitted to chemical examination by Mr.
Phillips, it was found to be very pure copper.
Alloys of copper have generally been found more durable than the
unmixed metal; and various patents have been taken out for the
fabrication of such compounds; but metallic sheets so composed
have been found to be too hard and brittle, and not to admit of
that flexibility which is necessary for their application to a
curved surface; the consequence of which has been, that they have
cracked upon the ship's bottom.
Sir H. Davy, on entering upon the examination of this subject,
very justly considered, that to ascertain the exact nature of the
chemical changes which take place in sea-water, by the agency of
copper, ought to be the first step in the enquiry; for, unless the
cause were thoroughly understood, how could the evil be remedied?
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