The manufacture of earth colours : $b With thirty-one illustrationsBersch, Josef
Science
The manufacture of earth colours : $b With thirty-one illustrations
Bersch, Josef
Coloring matter; Pigments
If burnt lime be left exposed to the air for some time, it again
gradually absorbs carbon dioxide and is reconverted into calcium
carbonate. When burnt lime is sprinkled with water it takes up the
latter avidly, becoming very hot and finally crumbling down to a very
friable white powder, consisting of slaked or hydrated lime (calcium
hydroxide, Ca(OH){2}). The considerable rise of temperature in
quenching the lime is due to the chemical combination of the calcium
oxide and water.
Both quick and slaked lime dissolve to a certain extent in water, and
impart strongly alkaline properties thereto, lime being one of the
strongest of bases. On exposure to the air, the solution of quick lime
in water (lime-water) quickly forms an opalescent superficial film
of calcium carbonate, and in a short time no more lime is present in
solution, the whole having been transformed into calcium carbonate,
which settles down to the bottom of the vessel as a very fine powder.
Limestone that consists entirely of calcium oxide and carbon dioxide
is of rare occurrence in Nature, foreign substances being nearly
always present. Since the nature of these admixtures is of the greatest
importance to the colour-maker, owing to the considerable influence
they exert on the suitability of the minerals for his purposes, it
is necessary that these extraneous substances occurring in limestone
should be more closely described.
Nearly all varieties of limestone contain certain proportions of
ferrous and ferric oxides. The presence of ferrous oxide, when the
relative amount is but small, cannot be detected by mere inspection;
and even many limestones containing really appreciable quantities of
ferrous oxide are pure white in colour so long as they are in large
lumps. If, however, such a limestone be reduced to powder and exposed
to the air for a short time, it gradually assumes a yellow tinge, the
depth of which increases with the length of exposure.
The cause of this change is due to the fact that ferrous oxide has a
great affinity for oxygen, by absorbing which it changes into ferric
oxide. (Ferrous oxide consists of FeO, ferric oxide of Fe{2}O{3}.)
Ferrous oxide and its compounds are of a pale green colour which is
not very noticeable, whereas ferric oxide has a very powerful yellow
colour, and consequently the limestone, when its superficial area has
been greatly increased by reduction to powder, assumes the yellow tinge
due to ferric oxide. A limestone exhibiting this property can evidently
not be used for making white earth colours, but is, at best, only
suitable for mixing with other colours.
Occasionally, limestone contains varying quantities of magnesia, and
when this oxide is present in large amount, changes into another
mineral known as dolomite. In many places this dolomite forms large
masses of rock, which, however, is not employed for making colours,
owing to the yellow shade imparted by the fairly large amount of ferric
oxide present.
_Gypsum_ (_Alabaster_)
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