The manufacture of earth colours : $b With thirty-one illustrationsBersch, Josef
Science
The manufacture of earth colours : $b With thirty-one illustrations
Bersch, Josef
Coloring matter; Pigments
This mineral occurs native in many places, and is frequently worked
for a number of purposes. Gypsum occurs in Nature in a great variety
of forms. The purest kind is met with either as water-clear crystals,
which cleave readily in two directions, or as transparent tabular
masses (selenite) which also cleave easily. Micro-crystalline
fine-grained gypsum is milk-white in colour, highly translucent and is
largely used, under the name of alabaster, in sculpture. Owing to its
low hardness, alabaster can be readily cut with a knife, and on this
account is frequently shaped by planing or lathe-turning.
Gypsum is generally met with in dense masses, which may be of any
colour, grey, blue and reddish shades being the most common, whilst
pure white is rarer. The dark-coloured varieties can only be used for
manurial purposes; but the white finds a twofold application as a
pigment, and, in the calcined state, for making plaster casts.
In point of chemical composition, gypsum consists of sulphate of lime,
or calcium sulphate (CaSO{4} + 2H{2}O). It is soluble in water, but
only in such small quantity that over 400 parts of the latter are
needed to dissolve one part of gypsum. On being heated to between 120°
and 130° C., gypsum parts with its two molecules of combined water and
becomes anhydrous calcium sulphate or burnt gypsum. When this latter
is stirred with water to a pulp, it takes up the water again, with
considerable evolution of heat, swelling up considerably and setting
quickly to a solid mass.
The number of substances exhibiting this property being small, burnt
gypsum is very frequently used for making casts of statuary, and for
stucco work in building. Finely ground white gypsum can also be used as
a pigment, but is inferior to calcium carbonate in covering power, and
is therefore seldom employed for this purpose, though frequently added
to other colours. The mineral known as muriacite or anhydrite consists
of anhydrous calcium sulphate; and is therefore similar in composition
to burnt gypsum; but it lacks the property of combining with water when
brought into contact therewith.
_Barytes, or Heavy Spar_
The mineral known as heavy spar occurs in very large quantities and in
numerous localities. It forms rhombic crystals, which are very often
extremely well developed and form flat plates of considerable size. A
remarkable peculiarity of this mineral is its high specific gravity,
which is due to the barium content. It is found native in all colours,
white being the most common.
Chemically, heavy spar is barium sulphate, BaSO{4}. It can be used as a
pigment _per se_, but only when prepared artificially, the trade name
for the product being permanent white, or blanc fixe. Powdered native
heavy spar, even when ground ever so fine, has not enough covering
power, this property being peculiar to the artificial product.
Public-domain text, read in full here on John Shaqi.
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