The manufacture of earth colours : $b With thirty-one illustrationsBersch, Josef
Science
The manufacture of earth colours : $b With thirty-one illustrations
Bersch, Josef
Coloring matter; Pigments
The mineral known as clay is, in all cases, a product of the
decomposition of other minerals, mainly felspar. This substance is a
double silicate of alumina and potash, K{2}O.Al{2}O{3}.(SiO{2}){6}.
Pure kaolin is Al{2}O{3}(SiO{2}){2} + 2H{2}O, or 46·50% silica, 39·56%
alumina, 13·9% water.
Clay may be supposed to have been formed by the conversion of felspar,
under the action of air and water, into silicate of alumina, the
silicate of potash being dissolved out. Being insoluble, the silicate
of alumina would be transported by the water, in a very fine state of
division, and finally deposited as a sediment, which in course of time
became a solid mass. This, when again brought into contact with water,
forms a very plastic pulp which, when dried and baked, forms a solid
mass, brick, which is no longer affected by water. Perfectly pure clay
forms a white mass, which, under the name of China clay or kaolin, is
used for making porcelain, and is only occasionally met with in large
quantities.
Pure kaolin is characterised by its great chemical indifference, being
decomposed only by strong alkalis and sulphuric acid. At the high
temperature of the pottery kiln, kaolin sinters to a very compact
mass, but cannot be fused, except when small quantities are subjected
to the intense heat of the oxyhydrogen flame, whereupon it fuses to a
colourless glass of great hardness.
In an impure state, silicate of alumina occurs frequently in Nature,
and then forms the minerals known under the generic names of clay,
loam, marl, etc. These impure clays contain varying proportions of
extraneous minerals which produce changes in the physical and chemical
properties. They are grey, blue or yellow in colour, the grey and blue
varieties mostly containing appreciable quantities of ferrous oxide,
whilst the yellow kinds contain ferric oxide. When fired, all of them
become yellow or red, the ferrous oxide being transformed into ferric
oxide by the heat. Some fairly white clays are high in lime, which
makes them fusible at high temperatures. In some very impure kinds,
even the comparatively low heat of the brick-kiln is sufficient to
cause partial fusion. For colour-making, the white clays, especially
kaolin and pipeclay, form a highly important material, being
procurable at very low prices and fairly easy to prepare.
The white clays are either used as pigments by themselves, or for
mixing with other colours of low specific gravity.
(B) YELLOW EARTHS
The number of yellow earths is large, but most of them exhibit a
certain similarity in chemical composition, the pigmentary principle in
the majority being either ferric oxide or ferric hydroxide. The former
is yellow, the latter brown, and the colour of the minerals resembles
that of the preponderating iron compound.
_Brown Ironstone_
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account