The manufacture of earth colours : $b With thirty-one illustrationsBersch, Josef
Science
The manufacture of earth colours : $b With thirty-one illustrations
Bersch, Josef
Coloring matter; Pigments
When it is desired to mix other pigments with a white substance, to
lighten the shade, permanent white can be specially recommended, since
it is quite insensitive to atmospheric influences and has no chemical
action on the colour, so that it can be used with even the most
delicate colours without risk. In this way, not only can the colours
be considerably cheapened, but over-dark colours can be shaded to the
desired extent. Another advantage of such mixtures is that a smaller
quantity of oil or varnish is required, barytes only needing about 8%
of its own weight of vehicle to form a workable mixture, whilst other
pigments take five times as much, or even more. In many cases the low
covering power of barytes enables large quantities to be added, and
this reacts favourably on the consumption of varnish.
Another barium mineral is witherite, or barium carbonate. This is not
used direct as a pigment, but--in contrast to heavy spar--is readily
soluble in hydrochloric acid, and therefore serves as raw material for
the preparation of artificial barytes and other barium compounds, the
first-named being obtained by treating a solution of barium chloride
with sulphuric acid, insoluble barium sulphate being precipitated.
_Talc_, _Soapstone_, _Steatite_
Talc occurs in Nature either as a pure white mass, of greasy lustre, or
occasionally as yellow, green or grey masses, all distinguished by a
peculiar greasy appearance and a soapy feel. This appearance is common
to all the minerals of the steatite group, and is the cause of their
generic name, soapstone. Although the steatites have a very low degree
of hardness--most of them can be scratched by the finger-nail--some
difficulty is encountered in reducing them to fine powder. Calcination
usually increases the hardness considerably, so that, in some cases,
the calcined mineral gives off sparks when struck with a steel
instrument.
Soapstone is composed of magnesium silicates, containing varying
proportions of magnesia and silica, together with a small quantity
of water, apparently in a state of chemical combination, a very high
temperature, approaching white heat, being required to effect its
complete expulsion, the residue then attaining the aforesaid high
degree of hardness. The composition of talc can be expressed by the
symbol H{2}Mg{2}(SiO{3}){4}, corresponding to 63·52% of silica,
31·72% of magnesia, and 4·76% of water. In some varieties of talc, a
portion (1–5%) of the magnesia is replaced by ferrous oxide. Talc is
quite unaffected by the action of dilute acids, boiling concentrated
sulphuric acid being required to decompose it, with separation of
silica.
Owing to its low specific gravity and chemical indifference, talc is
suitable for lightening the shade of certain lake pigments. It can also
be used as a pigment by itself, and also as a gloss on wall-paper, for
mixing with paper pulp, and for various other purposes.
_Clay_
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