The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
The variety of soot black known as lamp black is the best; it is used
for making copper-plate inks and black coach paints. Its price is
much higher than that of ordinary soot black; for the best qualities,
twenty times the price of an ordinary black is paid. The materials
already mentioned are used for making lamp black, fish oils and rancid
vegetable oils, and in recent times mineral oil and tar oils. In regard
to vegetable oils it is to be observed that it is advisable to use
very rancid oil, which gives a larger yield of soot; experience has
shown that a very rancid oil requires a larger quantity of oxygen to
burn without a smoky flame than a sweet oil. This indicates that a
portion of the carbon in the rancid oil is present in such a form that
it requires a higher temperature to burn it than is required for the
carbon in sweet oils. The use of rancid oils for making soot blacks has
thus two advantages, it is much cheaper and produces a larger yield.
The only disadvantage, and not a very important one, attending the
use of rancid oil is that the free fatty acids in these oils strongly
attack the metallic parts of the lamps. This is especially the case
with copper and brass; only such portions of the lamps as is absolutely
necessary should be made of these metals; all other parts, and in
particular the oil reservoirs, should be made of tin plate.
Since the development of the coal-tar industry oils distilled from
coal tar have come into commerce at low prices. These oils consist of
carbon and hydrogen and are equally volatile with the essential oils,
to which class turpentine belongs. There are two kinds of these tar
oils, light and heavy; they differ both in specific gravity and in
the boiling temperature, which ranges between tolerably wide limits.
When the burning qualities of these oils are examined, they show a
great difference in the quantities of oxygen necessary for complete
combustion with a white flame without smoke. The more oxygen an oil
requires to burn with a non-smoky flame, the more suited it is for the
manufacture of blacks. Generally speaking, the difficulty of completely
burning these oils is in proportion to their specific gravity and the
height of their boiling point.
By the distillation of rosin, oils are obtained which also consist of
carbon and hydrogen and form a useful material for the manufacture of
soot blacks. The mineral known as earth-wax or ozokerite, a substance
intermediate between asphaltum and petroleum, can also be used, but
since it is a solid it must be burnt in troughs.
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