The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
In burning light oils the arrangements can be very simply made; wicks
are not required and thus a considerable outlay is spared. In place
of the burner, shallow dishes are used into which the oil enters from
below, replacing that burnt away. It is necessary to cool these dishes
continuously from below, otherwise they would soon become so hot that
the greater part of the oil would evaporate without burning, and it
would also be very difficult to regulate the flame properly.
Black can be obtained from very resiniferous coal by burning in
furnaces with a regulated air supply. The product is, however,
generally largely contaminated by ash, and can only be used for common
purposes. Very resiniferous lignite gives a better product than coal;
the black can be partially separated from the ashes by shaking upon
water and then stirring, when the particles of ash sink to the bottom
and the light black floats on the top.
However carefully the manufacture of soot black is conducted, it
will always contain, in addition to carbon, varying quantities of
the products of distillation, partly solid and partly liquid. In
consequence of these admixtures the soot will not be pure black, but
will show a more or less brown tinge, which is clearly observed when
the black is smeared on white paper. At a certain thickness of the
layer of soot it will be seen that the colour is not black, but an
impure brown. When such soot, as it is taken from the chambers, is
chemically examined, it is found that it gives up a large quantity of
soluble matter to different chemical reagents. By proper treatment
it is possible to remove the admixtures almost completely, so that
nearly chemically pure carbon remains. Such pure carbon can be made by
boiling lamp black with strong caustic soda solution so long as the
liquid is coloured, and when caustic soda can dissolve nothing more,
the residue is boiled with _aqua regia_ until this no longer takes
up soluble matter. The black is then washed with water until free
from every trace of acid, and the residue dried. By this treatment
the soot is converted into a powder of the purest black hue which it
is possible to obtain. It is now no longer soot, but chemically pure
carbon in the non-crystalline form; heated upon platinum foil it burns
to pure carbonic acid without producing smoke or smell. In practice
the purification of the soot is not carried to the extent of producing
pure carbon; this would be accompanied by a diminished yield of the
pigment without increasing the commercial value of the product: the aim
of the manufacturer is simply to produce a substance of a pure black
appearance from the brown soot. To remove the brown substances present
in the crude soot the solvent action of caustic soda solution can be
used. The soot is several times boiled in iron pans with strong caustic
soda solution in order to dissolve the products of dry distillation.
It is superfluous to repeat this operation until fresh caustic soda
remains colourless.
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