The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
The concentrated extracts obtained in this apparatus should be mixed
with a little carbolic acid to prevent decomposition; they may then
be filled into barrels. The extracts may also be so far concentrated
by evaporation that they become syrupy. The tannins are readily
decomposed; they would be considerably altered if their solutions were
evaporated in open vessels. The extracts are therefore evaporated at a
very low temperature under diminished pressure in vacuum pans, which
are now much used for the concentration of solutions of substances,
such as sugar, which would be injured by heating above a certain
temperature. Essentially, a vacuum pan is a thick-walled copper vessel,
in which the liquid is warmed by a steam coil. It is connected with an
air pump, which exhausts the air at the commencement of an operation,
and afterwards steam. The liquid is thus constantly evaporated under
a low pressure. Extracts of tan-bark and dye-woods boil briskly
under these conditions at temperatures below 60° C., at which no
decomposition of the tannin or the colouring matter is to be feared.
When the solutions have been evaporated to the proper strength they are
run off directly into the packages in which they are to be despatched,
and in which they become syrupy or even solid masses, according to the
extent to which the evaporation has been driven.
The packages should be at once closed; the thick extract is thereby
most simply and safely prevented from decomposing, to which risk it
would be exposed by the access of mould spores. If these were already
present in the barrels or were communicated to the extract by the air,
they would either be killed by the hot liquid or would be prevented
from developing for a long time. In the closed vessels the extracts
remain completely unaltered.
The concentrated solution of colouring matter obtained by extracting
dye-woods in the above apparatus can be at once used, after dilution,
in the preparation of lakes and in dyeing, but it is not an extract in
the ordinary commercial sense of the term, _i.e._, it does not solidify
on cooling. To obtain solid extracts the concentrated solutions must
be evaporated; concentration with fire heat would be attended with
danger to the quality of the extract, steam heat is therefore used.
The liquid to be evaporated is brought into shallow steam-jacketed
pans, in which the operation is continued until the liquid solidifies
into a resin-like mass when dropped on cold stone. When sufficiently
evaporated the extract is allowed to solidify, broken into lumps,
and these packed whilst still warm into barrels lined with paper.
The lining is necessary on account of the hygroscopic nature of the
extracts; when they are exposed to the air they absorb water and form a
viscous fluid which soon becomes mouldy.
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