The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments — John Shaqi
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
=Sodium Carbonate= (Soda Crystals), Na₂CO₃.10H₂O = 286, is made in
enormous quantities in great works and in a very pure state. It forms
large transparent crystals, which effloresce in the air, losing a
large quantity of water, and so falling to a white powder. Although
this property does not interfere with the use of soda, since it is
generally used in solution, yet efflorescence should be as far as
possible avoided by keeping the salt in well-closed packages, because
effloresced soda dissolves more slowly than crystallised, since it has
to combine with water before it can enter into solution.
In the retail trade a form of soda is found which is adulterated with
very large quantities of Glauber’s salt. This is recognised by the
different form of the crystals. Manufacturers sell soda stating its
strength. The colour maker should only buy with this guarantee.
=Sodium Hydroxide= (Sodium Hydrate, Caustic Soda), NaOH = 40, comes
into commerce in the form of hard masses, the use of which would be
very convenient for the colour maker if it were not often very impure.
Thus it is better to prepare a solution oneself, which is accomplished
in the manner given above for caustic potash.
Caustic soda and caustic potash have similar properties; they have a
corrosive action on the skin, readily unite with carbonic acid from the
air, and separate the heavy metals from their solutions in the form of
hydrated oxides.
The strength of caustic soda solutions is given in the following table:—
+----------+----------+----------+----------+
| Specific | Caustic | Specific | Caustic |
| Gravity. | Soda | Gravity. | Soda |
| | per cent.| | per cent.|
+----------+----------+----------+----------+
| 2·00 | 77·8 | 1·40 | 29·0 |
| 1·85 | 63·6 | 1·36 | 26·0 |
| 1·72 | 53·8 | 1·32 | 23·0 |
| 1·63 | 46·6 | 1·29 | 19·0 |
| 1·56 | 41·2 | 1·23 | 16·0 |
| 1·50 | 36·8 | 1·18 | 13·0 |
| 1·47 | 34·0 | 1·12 | 9·0 |
| 1·44 | 31·0 | 1·06 | 4·7 |
+----------+----------+----------+----------+
Besides soda and caustic soda, few soda salts are used in colour
making. However, sodium nitrate (Chili saltpetre), NaNO₃, is frequently
used instead of ordinary saltpetre, from which it differs in being
deliquescent.
=Sodium Thiosulphate= (Hyposulphite), Na₂S₂O₃.5H₂O = 248, is a common
article of commerce, being much used by photographers; it is used in
a few cases in colour making. It forms large crystals with a somewhat
bitter taste, permanent in air and readily soluble in water.
=Sodium Chloride= (Common Salt), NaCl = 58·5, which has a little
application in colour making, is sufficiently pure in the form in which
it is generally used for household purposes.
SALTS OF THE ALKALINE EARTH METALS.
Public-domain text, read in full here on John Shaqi.
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