The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
The metals which are known as the alkali earth metals have much
similarity with the alkali metals in their compounds, with the
difference that their alkalinity is much less, and that their salts
are much less soluble in water. For colour making the compounds of
three of these metals—calcium, barium and magnesium—are used.
CALCIUM COMPOUNDS.
The most important calcium compounds are lime and carbonate and
phosphate of lime. Carbonate of lime is used as a pigment, and will be
dealt with in detail among the mineral colours; it will be but briefly
described here.
=Calcium Oxide= (Quicklime), CaO = 56.—When chalk and limestone, which
consist of calcium carbonate, are heated, carbonic acid is evolved, and
calcium oxide, commonly called quicklime, is left. For our purposes
only very pure quicklime is to be used. Its ordinary impurities are
iron oxide and magnesia: the former is found in lime made from red or
brown limestone; the latter in lime made from dolomitic limestone. The
presence of oxide of iron is recognised by the reddish tinge of the
quicklime; if magnesia be present, a small quantity of the quicklime,
when mixed with a very large quantity of water, leaves an insoluble
residue which consists of magnesia.
When quicklime and water are brought together they unite very
energetically and form calcium hydroxide or slaked lime. According to
the quantity of water used for slaking, either dry slaked lime, lime
paste, or milk of lime is produced, all of which find a use in colour
making.
=Calcium Hydroxide= (Slaked Lime), Ca(OH)₂ = 74.—In order to prepare
slaked lime, which contains lime united with just the necessary
quantity of water, the pieces of quicklime are sprinkled with water
from a watering can. The water is rapidly taken up and the sprinkling
is repeated until the lumps begin to fall to a fine powder; in the
process the lime becomes very hot. The slaked lime is then passed
through a sieve in order to separate the larger pieces of quicklime
which have not been slaked; the powder must be kept in well closed
packages, since it energetically absorbs carbonic acid out of the air.
If so much water is added to the lime that a homogeneous wet mass is
formed which can be readily moved with a shovel, one has then lime
paste, which can be conveniently kept in pits as the masons do; it may
be stored in this way for many months without appreciable alteration,
still it is better to keep it covered. To prepare milk of lime, so
much water is used in slaking that a milky liquid is formed, or the
lime paste is mixed up in the proper quantity of water. Slaked lime
dissolves in 700 to 800 parts of water; on standing, the undissolved
slaked lime settles to the bottom of the milk of lime: thus it is
better to prepare milk of lime immediately before use, and to stir it
well to prevent the settling of the solid particles.
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