The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
Slaked lime in one of its forms is often used instead of the more
costly caustic soda in order to precipitate metallic oxides from their
salts.
At times one finds a too strongly burnt lime, so-called “dead-burnt”
lime, which is very slowly slaked by water. Such quicklime is slaked by
allowing it to lie in water for days, or by means of hot water, which
accomplishes the slaking more quickly.
=Calcium Carbonate=, CaCO₃ = 100, is found naturally in large
quantities as chalk, which consists of the skeletons of extremely small
animals. By powdering and levigating, it is converted into a soft
powder, which is used to lighten the shade of lakes and other colours.
=Calcium Sulphate= (Gypsum), CaSO₄.2H₂O = 172.—This mineral, when
finely powdered, is added to some colours.
=Calcium Phosphate= (Bone Ash), Ca₃(PO₄)₂ = 310, is sometimes used to
lighten the shade of certain colours which might be injured by calcium
carbonate. It comes in large quantities as a fine, white powder from
South America. Naturally, only quite white bone ash can be used; if not
completely burnt it is grey, and will then impair the shade of colours
with which it is mixed.
=Magnesium Carbonate= (Magnesia), MgCO₃ = 84, is also used as an
addition to colours in order to obtain pale shades. It is most cheaply
obtained by dissolving magnesium sulphate (Epsom salts) in water and
adding soda solution so long as a precipitate forms, which is then
washed and dried. The magnesium carbonate prepared in this way is a
very fine, light powder, insoluble in water, which can be mixed with
the most delicate colours without harming them. White magnesia is an
extremely light powder, which may be used when it can be bought at as
low a price as the above preparation.
=Barium Compounds.=—The raw material used for the preparation of barium
pigments is either barium sulphate (barytes, heavy spar) or barium
carbonate (witherite). The latter is much more rare than barytes, which
is almost exclusively employed in the preparation of barium compounds.
The barium compounds of particular importance for our purpose are
barium chloride and nitrate.
=Barium Chloride=, BaCl₂.2H₂O = 244.—This salt is now a common article
of trade, and can be bought at a low price. When pure it forms
colourless crystals readily soluble in water. If the colour maker is
able to get cheap barytes and fuel, it may be advantageous for him to
prepare barium chloride himself.
To prepare barium chloride from barytes, the latter is very finely
ground and levigated, intimately mixed with coal, and the mixture
subjected to a very high temperature, when barium sulphide is formed,
which is dissolved by washing out the mass with water and converted
into barium chloride by adding hydrochloric acid, sulphuretted hydrogen
being evolved.
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