The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
To test alum for iron yellow prussiate of potash is used, which gives
a blue precipitate with ferric salts. The test is carried out by
dissolving 10 grammes of alum in 1 litre of water, placing the solution
in a tall, narrow cylinder standing on white paper, adding 10 to 20
drops of a saturated solution of yellow prussiate, and well stirring.
On looking down through the liquid, if a distinct colouration is at
once evident, the alum contains much iron, and must be recrystallised;
indeed, the crystals would generally be coloured yellow. On the
contrary, if the solution does not show a blue tint until after
standing several days, the alum contains but a small quantity of
iron, and can be used for most purposes without further purification.
Alum quite free from iron is a rare commercial article; the test will
generally show a feeble blue colouration. If this is not intense and
no blue precipitate is deposited at the bottom, the alum is tolerably
pure, and can be used in colour works. The longer the time before the
blue colouration appears the poorer is the alum in iron.
=Soda Alum=, NaAl(SO₄)₂.12H₂O = 458, is made in some alum works. It
has the greatest similarity in properties with the potash salt, but
is distinguished by a much greater solubility in water and more rapid
efflorescence in air. Soda alum can be bought at varying prices; that
containing iron is much cheaper than that free from iron. When the
latter is to be bought at a fair price it is to be preferred to potash
alum, since, as we shall show later, it contains a larger proportion of
alumina.
=Ammonia Alum=, (NH₄)Al(SO₄)₂.12H₂O = 453.—This compound of aluminium
sulphate and ammonium sulphate is now often met with; the more
expensive potassium sulphate in ordinary alum is replaced by ammonium
sulphate, which is cheaply obtained from the ammoniacal liquor of the
gas works.
Ammonia alum is better for our purpose than potash alum since it
contains more alumina, is generally cheaper and dissolves more easily
in water. Unfortunately most commercial ammonia alum contains so much
iron that it has to be recrystallised before it can be used in colour
works.
One hundred parts of water dissolve at different temperatures the
quantities of ammonia alum given in the table:—
Public-domain text, read in full here on John Shaqi.
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