The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
The German or Austrian method of making white lead is also known as the
chamber process, since the formation takes place in closed chambers,
constructed of wood or masonry. In the older processes, cast lead
sheets were bent double and hung on cross bars in a wooden box with
a water-tight bottom, with the precaution that the plates did not
touch. A number of these boxes, generally 90, were arranged in a hot
room, each box being about 1·6 metre long, 0·4 metre wide and 0·3
metre high. On the bottom of each box was poured a mixture of vinegar
or dilute acetic acid and wine refuse, and the box was covered with
a well-fitting lid. The temperature of the room was gradually raised
week by week; during the first week remaining at 25° C., during the
second at 38° C., the third at 45° C. At the commencement of the
fourth week the temperature was raised to 50° C., at which it was kept
for a fortnight. At this high temperature a considerable quantity of
acetic acid is evaporated, causing the formation of lead acetate,
which is converted, by the carbonic acid evolved from the wine refuse,
into basic lead carbonate. When the proper temperatures have been
maintained, on opening the boxes almost all the lead is found changed
into white lead, which is knocked off, and the residual lead used in
casting new plates. It is easy to conceive that the boxes may be well
replaced by brick chambers, in which a large number of lead plates
are brought and into which acetic acid vapours and carbonic acid are
introduced after the room has been closed. Chambers are used which can
contain 12,000 to 12,500 kilogrammes of lead.
These chambers, in which the lead plates are hung upon wooden supports,
have an opening immediately above the bottom, which is connected with
a retort in which vinegar, containing 4 to 5 per cent. of acetic acid,
is boiled. After about 12 hours, by the simultaneous action of the
vapours of acetic acid and the oxygen of the air, lead acetate is
formed. Carbonic acid is now led into the chambers. The carbonic acid
is obtained by burning charcoal in a cylindrical furnace; it is cooled
by being passed through a long iron tube before it enters the chamber.
For 12,500 kilogrammes of lead there are required every day about 482
litres of dilute acetic acid, obtained by mixing strong acetic acid
with water until the mixture contains 4·5 per cent. of the acid, and
18 kilogrammes of charcoal, from which the carbonic acid is obtained.
The time required is 5 or 6 weeks, and the residue of unaltered lead
varies from 10 to 35 per cent.
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