The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
The white lead obtained by this process is quite usable, but the
process has the considerable disadvantage that there is no control
over the quantities of materials used. In order to produce a certain
quantity of white lead of a certain composition, definite quantities
of lead, oxygen, acetic acid and carbonic acid are necessary. If,
then, the apparatus can be so arranged that the quantities of material
employed can be accurately measured, a great advance will have been
made, for the operation will be no longer conducted at random, but
under definite unchangeable conditions. The quantities of carbonic acid
and acetic acid can be calculated beforehand. The volumes of the gases
required may be measured without difficulty by meters of the type used
for measuring coal gas. Upon this principle are based a number of more
modern methods.
[Illustration: FIG. 11.]
According to the process of Major, the vapours of water and acetic
acid are introduced at the same time into the chambers filled with
lead plates, in order to produce basic lead acetate. This part of the
process requires about 12 hours. Then carbonic acid is introduced; it
is produced by burning charcoal in an iron cylinder, through which air
is forced. By means of this carbonic acid, which is at a comparatively
high temperature, about 60° C., the lead acetate is quickly changed
into white lead. A portion of the lead acetate remains undecomposed;
in order to remove this, at the close of the operation ammonia is
injected, which decomposes the lead salt. The ammonia salts now present
are finally driven out by means of superheated steam. Major’s apparatus
is depicted in Fig. 11. _A_ and _B_ are chambers with horizontal
gratings upon which the lead lies; _C_ is the furnace for burning the
charcoal, provided with a fan. The products of combustion from _C_ pass
under the boiler _D_, their passage being regulated by the valve, _a_;
they then heat the boiler _E_, containing acetic acid, and enter the
chambers, _A_ and _B_, through the flue, _b_, or are directed by the
valve in _b_ into the chimney, _d_. The gases, after passing through
the chamber, find an exit at _e_. The steam pipe, _f_, conducts steam
into the boiler _E_, through _g_, and also into the chambers, _A_ and
_B_, thus heating them and providing the necessary moisture; _h_ is the
funnel for filling _E_; the pipe, _k_, carries the acetic acid vapours
into the chambers. After the thin lead plates have been brought into
the chambers they are closed and the temperature raised to 49° to 60°
C., steam and acetic acid vapours are led in for 10 to 20 hours in
order to form the basic acetate, then the furnace gases are introduced
at a temperature of 60° C. The white lead obtained in this manner can
be finished in the ordinary way by washing and grinding, but it is
better to remove the lead acetate by introducing ammonia, and then hot
air or superheated steam, as previously stated.
[Illustration: FIG. 12.]
[Illustration: FIG. 13.]
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