The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
The process is complete in 2 to 4 weeks. Gartner, working according to
this process with 150 kilogrammes of lead in a chamber 1·26 metre long,
0·78 metre high and 0·78 metre wide, obtained good white lead in 28
days.
The apparatus designed by H. Kirberg for the manufacture of white lead
is illustrated in Figs. 12, 13 and 14. The lead plates are hung upon
the laths, _a_, in the chambers; the supports of the laths, _b_, go
through the slits, _c_, in the supports, _d_, and project through the
walls at _e_. The carriers, _b_, hang from bolts by brass wire. By
striking the end of the laths, _e_, they are made to swing so that the
white lead loosely adhering to the lead plates is shaken off and fresh
surfaces of metal are exposed. The openings in the walls through which
the ends of the laths project are closed by indiarubber. In order to
prevent the production of dust when the chambers are emptied, water is
introduced in a fine spray upon the lead plates from the copper tubes,
_v_, placed under the roof of the chamber. The water washes off the
remains of the white lead from the plates.
[Illustration: FIG. 14.]
In a similar manner, the white lead process may be carried out in a
shorter time when the gases enter the chamber under increased pressure;
but this is attended with difficulties, since continuous supervision of
the apparatus and of the tightness of the chamber is necessary.
[Illustration: FIG. 15.]
The apparatus of W. Thompson (Fig. 15) consists of a chamber, _A_,
constructed with a false roof, _B_, to carry off the condensed vapours,
and provided at both sides with doors, through which the waggons,
carrying the lead, are introduced and removed. The pipes, _n_, which
convey air and carbonic acid, are provided with branches, _e_, which
reach to the sides of the chamber, and are joined to the perforated
tubes, _D_. The pipes, _n_, are provided with reservoirs, _b_, which
prevent the too rapid entry of the air or carbonic acid, and at the
same time give a sufficient heating surface. Upon the waggon, _E_, are
the frames, _v_, which support the lead plates. The plates may be solid
or gratings; they are 3 to 12 millimetres thick, and are arranged at
intervals of about 25 millimetres in the frames. The troughs, _F_, for
the reception of the acetic acid are filled from the reservoir, _Z_.
The steam pipe, _C_, effects the evaporation of the acid; the steam
pipe, _d_, heats the chamber at the commencement of the process, and
also when _C_ is out of use. When the chamber is filled with lead, the
troughs, _F_, are filled with acetic acid of 5 per cent. strength. The
chambers are closed, and steam is led through _C_ and _d_ until the
temperature in the chamber reaches 25° to 50° C., and the evaporation
of the acid begins. Then air is forced in under a small pressure
through _n_, _e_, _D_ during 3 to 4 days, after which follows a mixture
of equal parts of carbonic acid and air, continued until the formation
of white lead is complete.
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