The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
When plates 3 millimetres thick are used,
and the temperature is gradually raised from 25° to 50° C., about 12
days are required; but if the plates are 12 millimetres thick, 28
days are necessary. For the proper carrying out of this process it is
important that the temperature of the chamber should be very gradually
raised from 25° to 50° C.
In the process of P. Rey molten lead is poured in a thin stream into
water, and the “granulated” metal then placed in vessels, in a layer
30 centimetres thick, upon a grating 5 centimetres above the bottom.
In the bottom are narrow tubes which, reaching above the lead, serve
to admit air. Acetic acid is allowed to flow over the lead from vessel
to vessel. In order to obtain the proper solution, a layer of lead, 2
metres thick, is necessary, so that 6 to 7 vessels are arranged, one
above the other. If lead acetate solution be used, the layer of lead
need only be 1·2 metre thick. The solution of basic lead acetate is
then treated with carbonic acid according to the ordinary process.
In addition to the modifications of the German white lead process which
have been described, many others have been proposed. The principle of
many of these methods is, that finely divided lead is much more rapidly
converted into white lead than lead in the form of plates; finely
divided lead exposes an enormously greater surface to the action of the
acetic acid and other materials than do lead plates.
In Rostaing’s method the lead is changed into very small pellets, by
allowing the melted metal to flow on to a rapidly rotating iron disc;
the molten lead, in consequence of the centrifugal force due to the
rapid rotation, assumes the form of very small drops, which are thrown
off the disc and cooled in a vessel of cold water.
Torassa recommends that lead, obtained in pellets by pouring into
cold water, should be brought into a rapidly rotating vessel, whereby
the greater part will be converted into fine dust (?). This lead dust
is said to be then converted into white lead by simple exposure to
air, lead oxide being first formed, and from it basic lead carbonate.
This process is not workable on a large scale. The rapid oxidation of
finely divided lead by air has been applied by several inventors to
the manufacture of white lead. The processes of Woods, M’Cannel and
Grüneberg are founded upon this transformation. In essentials they are
as follows: lead is finely divided in iron or earthenware cylinders,
and either carbonic acid and air, or a mixture of these with acetic
acid vapour, are introduced by means of the axle of the cylinders.
Public-domain text, read in full here on John Shaqi.
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