The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-MakingSindall, R. W. (Robert Walter)
History
The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-Making
Sindall, R. W. (Robert Walter)
Papermaking
Its composition is represented by the formula C_{6}H_{10}O_{5}.
The celluloses obtained from various plants are not identical either in
physical structure and chemical constitution, or as to their behaviour
when employed for paper-making. In fact, the well-known differences
between the raw materials used for paper-making, and also between the
numerous varieties of finished paper, are to be largely accounted for
and explained by a careful study of the cellulose group, particularly
with reference to the microscopic characteristics and the chemical
composition of the individual species.
The only vegetable substance which may be regarded as a simple
cellulose is cotton, all others being compound celluloses of varying
constitution, the nature of which cannot be appreciated without a
considerable knowledge of chemistry. The classification of such plants,
therefore, in a book of this description must be limited to certain
distinctions having some immediate practical bearing on the question of
paper manufacture.
_Cotton._--Regarded as the typical simple cellulose, containing 91 per
cent. of cellulose, and remarkable for its resistance to the action of
caustic soda.
_Linen._--The cellulose isolated from flax by treatment with alkali or
caustic soda cannot readily be distinguished from cotton cellulose by
chemical analysis or reactions. The difference is almost entirely a
physical one.
Flax is a typical compound cellulose, to which has been given the name
pecto-cellulose on account of certain properties. Other well-known
plants of this class are ramie, aloe, "sunn hemp," manila.
_Esparto._--The cellulose isolated from esparto differs in composition
from cotton cellulose:--
Carbon 41·0
Hydrogen 5·8
Oxygen 53·2
-----
100·0
-----
It is regarded as an oxycellulose, being readily oxidised by exposure
to air at 100° C. Other oxycelluloses familiar to the paper-maker are
straw, sugarcane, bamboo.
_Wood._--The difference between wood and the plants already mentioned
is expressed by the term lignified fibre or ligno-cellulose. This term
is used to indicate that the wood is a compound cellulose containing
non-fibrous constituents, to which has been given the name lignone.
Jute is another example of this class.
* * * * *
These distinctions may be exemplified by reference to a simple
experiment. If three papers, such as a pure rag tissue or a linen
writing, an ordinary esparto printing, and a cheap newspaper containing
about 80 per cent. of mechanical wood, are heated for twenty-four
hours in an oven at a temperature of 105° C., the first will undergo
little, if any, change in colour, while the others will be appreciably
discoloured, the mechanical wood pulp paper most of all.
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