The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-MakingSindall, R. W. (Robert Walter)
History
The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-Making
Sindall, R. W. (Robert Walter)
Papermaking
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Fibre. | Cellulose, per cent.
------------------+-------------------------
Cotton | 91·0
Flax | 82·0
Hemp | 77·0
Ramie | 76·0
Manila | 64·0
Jute | 64·0
Wood (pine) | 57·0
Bagasse | 50·0
Bamboo | 48·0
Esparto | 48 to 42
Straw | 48 to 40
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_The Properties of Cellulose._--Cellulose is remarkably inert towards
all ordinary solvents such as water, alcohol, turpentine, benzene,
and similar reagents, a property which renders it extremely useful in
many industries, with the result that the industrial applications of
cellulose are numerous and exceedingly varied.
_Solubility._--Cellulose is dissolved when brought into contact with
certain metallic salts, but it behaves quite differently to ordinary
organic compounds. Sugar, for example, is a crystalline body soluble
in water, and can be recovered in a crystalline state by gradual
evaporation of the water. Cellulose under suitable conditions can be
dissolved, but it cannot be reproduced in structural form identical
with the original substance.
If cellulose is gently heated in a strong aqueous solution of zinc
chloride, it gradually dissolves, a thick syrupy mass being obtained,
which consists of a gelatinous solution of cellulose. If the mixture
is diluted with cold water, a precipitate is produced consisting of
cellulose hydrate intimately associated with oxide of zinc, which
latter can be dissolved out by means of hydrochloric acid. The
resulting product is not, however, the original substance, but a
hydrated cellulose, devoid of any crystalline structure.
Cellulose is also soluble in ammoniacal solutions of cupric oxide, from
which it can be precipitated by acids or by substances which act as
dehydrating agents, _e.g._, alcohol.
_Hydrolysis._--An explanation of the behaviour of cellulose towards the
solvents already mentioned, and towards acid and alkali, requires a
reference to its chemical composition.
The substance is a compound of carbon, hydrogen, and oxygen represented
by the formula
C_{6}H_{10}O_{5}
being one of a class of organic compounds known as carbohydrates,
so designated because the hydrogen and oxygen are present in the
proportions which exist in water.
Water = Hydrogen + Oxygen
H_{2} + O.
The H_{10}O_{5} in the cellulose formula corresponds to 5 (H_{2}O).
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