Colloidal solutions possess only a very feeble osmotic pressure. The
lowering of the freezing point and the other corresponding constants are
also quite insignificant. This arises from the fact that the molecules of a
colloid are extremely large when compared with those of a crystalloid. For
example let us take colloidal substance whose molecular weight is 2000. A
solution containing 40 grammes per litre would have an osmotic pressure
only one-fiftieth of that of a {38} solution of similar strength of a
crystalloid whose molecular weight was 40.
Not only so, but on measuring the molecular concentration, the osmotic
pressure, and the other constants of a colloidal solution, we find values
even lower than those which we should expect from a consideration of its
molecular weight. This is probably due to the tendency of a colloid to
polymerization, i.e. to form groups or associations of molecules. Suppose,
for instance, that the molecules of a colloidal solution are aggregated
into groups of ten. Since each group plays the part of a simple molecule,
the osmotic pressure will be ten times less than that corresponding to the
quantity of the solute present. Such a group of molecules is called by
Naegeli a "micella."
Similar phenomena of aggregation may be observed in the molecules of many
inorganic substances. The molecule of iodine, for example, is monatomic at
1200deg C., but becomes diatomic at the ordinary temperature. Sulphur at
860deg C. is a gas with a vapour density of 2.2, while at 500deg C. its
vapour density rises to 6.6. In both of these cases two or more molecules
of the element have been condensed into one as a result of the fall of
temperature.
We frequently find that two successive cryoscopic observations on the
freezing point of the same colloidal solution will vary. This is due to the
extreme sensitiveness of the micellae, which absorb or abandon their extra
molecules under the slightest influence. This mobility in the constitution
of the micellae appears to be one of the principal causes of the peculiar
properties of colloidal solutions.
The phenomenon of polymerization appears to be reversible. The micellae are
formed under certain conditions, and are disintegrated when these
conditions are removed. The osmotic pressure varies in the same manner,
diminishing with polymerization and augmenting with the disintegration of
the micellae. One may easily understand what an important role is played by
this alternate polymerization and disintegration in the phenomena of life.
Most colloidal substances are precipitated from their solutions by the
addition of very small quantities of electrolytic {39} solutions.
Non-electrolytic solutions do not appear to provoke this precipitation.
This is not a chemical action, for an exceedingly small quantity of an
electrolyte is able to precipitate an indefinite quantity of the colloid.
The precipitation is probably due to the electric charges carried by the
dissociated ions of the electrolytes.
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