When an electric current is passed through a colloid solution, the course
of the molecules of the colloid is sometimes towards the cathode and
sometimes towards the anode, according to the nature of the colloid and of
the solvent. This displacement would appear to indicate a difference of
electric potential between the molecules of the colloid and those of the
solvent. Hardy has shown that in an alkaline solution the molecules of
albumin travel towards the anode, while in an acid solution they travel
towards the cathode.
_Metallic Colloids._--Carey Lea and afterwards Crede succeeded in obtaining
silver in colloidal solution by ordinary chemical means. Professor Bredig
has introduced a more general method of obtaining a number of metals in
colloidal solutions in a state of great purity. He causes an electric arc
to pass between two rods of the metal immersed in distilled water. The
cathode is thus pulverized into a very fine powder which rests in
suspension in the liquid, constituting a colloidal solution. Bredig has in
this way prepared sols of platinum, palladium, iridium, silver, and
cadmium.
_Catalytic Properties of Colloids._--Catalysis is the property possessed by
certain bodies of initiating chemical reaction. The mass of the catalyzing
body has no definite proportion to that of the substances entering into the
reaction, and the appearance of the catalyzer is in no way altered by the
reaction.
Ostwald has shown that catalysis consists essentially in the acceleration
or retardation of chemical reactions which would take place without the
action of the catalyzer, but more slowly.
Catalytic reactions are very numerous in chemistry. The inversion of sugar
by acids, the etherization of alcohol by sulphuric acid, the decomposition
of hydrogen peroxide by {40} platinum black are all instances of catalysis.
Fermentation by means of a soluble ferment or diastase, a phenomenon which
may almost be called vital, is also a catalytic action. The action of
pepsin, of the pancreatic ferment, of zymase, and of other similar ferments
has a great analogy with the purely physical phenomenon of catalysis. The
diastases are all colloids, and so are many other catalyzers.
A catalyzer is a stimulus which excites a transformation of energy. The
catalyzer plays the same role in a chemical transformation as does the
minimal exciting force which sets free the accumulation of potential energy
previous to its transformation into kinetic energy. A catalyzer is the
friction of the match which sets free the chemical energy of the powder
magazine.
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