The division into solutions and pseudo-solutions or suspensions is also an
arbitrary one. A true solution is also a suspension of the molecules of the
solute. There is no essential difference between a solution and a
suspension, but only a difference in the size of the molecules, or
agglomerations of molecules, in one case so small as to be transparent, and
in the other case just big enough to diffuse light. There are moreover many
properties common to colloidal solutions and suspensions of fine powders,
such as kaolin, mastic, charcoal, or Indian ink. These particles in
suspension are precipitated by solutions of electrolytes in a manner
similar to the coagulation of colloids.
The surface of every liquid is covered by a very thin layer, a sort of
membrane slightly differentiated from the rest of the liquid. This membrane
may be a chemical one, a pellicular precipitate like that which is formed
by the contact of two membranogenous liquids. On the other hand, the
membrane may not differ from the subjacent liquid in chemical composition,
but only in physical properties. If we {42} consider the molecules in the
middle of a liquid, each molecule is subjected to the cohesive attraction
of molecules on every side, attractions which neutralize one another. At
the surface of the liquid, however, there are quite other conditions of
equilibrium. There each molecule is drawn downwards towards the centre of
the liquid, and there is no compensating attraction in an opposite
direction. The resultant pressure is normal to the surface of the liquid,
and is mechanically equivalent to an elastic membrane which tends to
diminish the surface, and hence the volume of the liquid. We may therefore
regard this surface tension as acting the part of a veritable physical
membrane.
There is a still further differentiation of the surface of a liquid. When
the liquid is not a simple one, but complex as in a solution, we find that
the concentration of the solute is greater at the surface than in the
interior. This is the so-called phenomenon of "adsorption," which is
another cause for the production of a physical membrane covering the
surface of a liquid.
Substances in a colloidal state have a great tendency to form these
chemical or physical membranes at the point of contact between the
colloidal solute and the solvent. This is probably the reason why the
coagulum of a colloidal liquid usually presents a vacuolar or spongy
structure.
* * * * *
{43}
CHAPTER V
DIFFUSION AND OSMOSIS
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