Bredig has studied the catalytic decomposition of hydrogen peroxide by
metallic colloids prepared by his electric method. He found that 1
atom-gramme of colloidal platinum gives a sensible catalytic effect when
diluted with 70 million litres of water. Caustic soda and other chemical
substances inhibit the catalytic action of colloidal platinum in the same
way as they inhibit the fermenting action of diastase. The curve of
decomposition of hydrogen peroxide by colloidal platinum may be compared
with the curve of fermentation by emulsin. Both are equally affected by the
addition of an alkali. Many other chemical and physical agents have a
similar inhibitory action on the catalysis of colloidal metals and on
diastasic fermentation. Thus a mere trace of sulphuretted hydrogen or
hydrocyanic acid will paralyse the action of a colloidal metal, just as it
does that of a ferment. This is what Bredig calls the poisoning of metallic
ferments.
We may hope that the further study of catalysis, a purely physico-chemical
phenomenon, may throw more light on the mechanism of diastasic
fermentation, which is essentially a vital reaction.
It must not be forgotten that all classification is artificial and
arbitrary, and only to be used as long as it facilitates study. This
observation is particularly applicable to the classification of substances
into crystalloids and colloids. {41} There is no sharp line between the two
groups, the passage is gradual, and it is impossible to say where one group
ends and the other begins. Many colloids such as haemoglobin are
crystallizable, and many crystallizable substances are coagulable. Many
substances appear at one time in the crystalloid state and at another time
in the colloidal state, so that instead of dividing substances into
colloids and crystalloids, we should rather consider these expressions as
denoting different phases assumed by the same substance.
In order to define clearly our various classes and divisions, we are apt to
exaggerate slight differences of properties or composition. We say that
colloids have no osmotic pressure, whereas in fact the osmotic pressure of
the colloids though feeble plays a very important part in the phenomena of
life.
So in other departments of science--a factor which is almost infinitesimal
may yet exercise a vast influence on the results. It is by infinitesimal
variations of pressure, a thousandth of a millimetre or less, that we
obtain the various degrees of penetration in the Roentgen rays.
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