The Molecular Tactics of a CrystalKelvin, William Thomson, Baron
Science
The Molecular Tactics of a Crystal
Kelvin, William Thomson, Baron
Crystallography, Mathematical
§ 21. Consider, for example, the ideal case of a crystal consisting
of hard equal and similar tetrahedronal solids all same-ways oriented.
A thin plate of crystal cut parallel to any one set of the faces of
the constituent tetrahedrons would have very different properties on
its two sides; as the constituent molecules would all present points
outwards on one side and flat surfaces on the other. We might expect
that the two sides of such a plate of crystal would become oppositely
electrified when rubbed by one and the same rubber; and, remembering
that a piece of glass with part of its surface finely ground but not
polished and other parts polished becomes, when rubbed with white
silk, positively electrified over the polished parts and negatively
electrified over the non-polished parts, we might almost expect that
the side of our supposed crystalline plate towards which flat faces
of the constituent molecules are turned would become positively
electrified, and the opposite side, showing free molecular corners,
would become negatively electrified, when both are rubbed by a rubber
of intermediate electric quality. We might also from elementary
knowledge of the fact of piezo-electricity, that is to say, the
development of opposite electricities on the two sides of a crystal
by pressure, expect that our supposed crystalline plate, if pressed
perpendicularly on its two sides, would become positively electrified
on one of them and negatively on the other.
§ 22. Intimately connected with the subject of enclosing cells for
molecules of given shape, assembled homogeneously, is the homogeneous
packing together of equal and similar molecules of any given shape. In
every possible case of any infinitely great number of similar bodies
the solution is a homogeneous assemblage. But it may be a homogeneous
assemblage of single solids all oriented the same way, or it may be
a homogeneous assemblage of clusters of two or more of them placed
together in different orientations. For example, let the given bodies
be halves (oblique or not oblique) of any parallelepiped on the two
sides of a dividing plane through a pair of parallel edges. The two
halves are homochirally[8] similar; and, being equal, we may make a
homogeneous assemblage of them by orienting them all the same way
and placing them properly in rows. But the closest packing of this
assemblage would necessarily leave vacant spaces between the bodies:
and we get in reality the closest possible packing of the given bodies
by taking them in pairs oppositely oriented and placed together to form
parallelepipeds. These clusters may be packed together so as to leave
no unoccupied space.
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