The Molecular Tactics of a CrystalKelvin, William Thomson, Baron
Science
The Molecular Tactics of a Crystal
Kelvin, William Thomson, Baron
Crystallography, Mathematical
Whatever the number of pieces in a cluster in the closest possible
packing of solids may be for any particular shape, we may consider each
cluster as itself a given single body, and thus reduce the problem to
the packing closely together of assemblages of individuals all sameways
oriented; and to this problem therefore it is convenient that we should
now confine our attention.
§ 23. To avoid complexities such as those which we find in the familiar
problem of homogeneous packing of forks or spoons or tea-cups or bowls,
of any ordinary shape, we shall suppose the given body to be of such
shape that no two of them similarly oriented can touch one another
in more than one point. Wholly convex bodies essentially fulfil this
condition; but it may also be fulfilled by bodies not wholly convex, as
is illustrated in Fig. 11.
[Illustration: Fig. 11.]
§ 24. To find close and closest packing of any number of our solids
_S_{1}_, _S_{2}_, _S_{3}_ ... of shape fulfilling the condition of § 23
proceed thus:--
(1) Bring _S_{2}_ to touch _S_{1}_ at any chosen point _p_ of its
surface (Fig. 12).
(2) Bring _S_{3}_ to touch _S_{1}_ and _S_{2}_, at _r_ and _q_
respectively.
(3) Bring _S_{4}_ (not shown in the diagram) to touch _S_{1}_, _S_{2}_,
and _S_{3}_.
(4) Place, any number of the bodies together in three rows continuing
the lines of _S_{1}S_{2}_, _S_{1}S_{3}_, _S_{1}S_{4}_, and in three
sets of equi-distant rows parallel to these. This makes a homogeneous
assemblage. In the assemblage so formed the molecules are necessarily
found to be in three sets of rows parallel respectively to the three
pairs _S_{2}S_{3}_, _S_{3}S_{4}_, _S_{4}S_{2}_. The whole space
occupied by an assemblage of _n_ of our solids thus arranged has
clearly _6n_ times the volume of a tetrahedron of corresponding points
of _S_{1}_, _S_{2}_, _S_{3}_, _S_{4}_. Hence the closest of the
close packings obtained by the operations (1) ... (4) is found if we
perform the operations (1), (2), and (3) as to make the volume of this
tetrahedron least possible.
[Illustration: FIG. 12]
§ 25. It is to be remarked that operations (1) and (2) leave for (3)
no liberty of choice for the place of _S_{4}_, except between two
determinate positions on opposite sides of the group _S_{1}_, _S_{2}_,
_S_{3}_. The volume of the tetrahedron will generally be different for
these two positions of _S_{4}_, and, even if the volume chance to be
equal in any case, we have differently shaped assemblages according as
we choose one or other of the two places for _S_{4}_.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account