The Molecular Tactics of a CrystalKelvin, William Thomson, Baron
Science
The Molecular Tactics of a Crystal
Kelvin, William Thomson, Baron
Crystallography, Mathematical
§ 29. In this assemblage we have what I call ‘close order’ or ‘close
packing.’ For closest of close packings the volume of the tetrahedron
(§ 24) of corresponding points of _S_{1}_, _S_{2}_, _S_{3}_, and
_S_{4}_ must be a minimum, and the least of minimums if, as generally
will be the case, there are two more different configurations for
each of which the volume is a minimum. There will in general also be
configurations of minimax volume and of maximum volume, subject to
the condition that each body is touched by twelve similarly oriented
neighbours.
§ 30. Pause for a moment to consider the interesting kinematical
and dynamical problems presented by a close homogeneous assemblage
of smooth solid bodies of given convex shape, whether perfectly
frictionless or exerting resistance against mutual sliding according to
the ordinarily stated law of friction between dry hard solid bodies.
First imagine that they are all similarly oriented and each in contact
with twelve neighbours, except outlying individuals (which there must
be at the boundary if the assemblage is finite, and each of which is
touched by some number of neighbours less than twelve). The coherent
assemblage thus defined constitutes a kinematic frame or skeleton
for an elastic solid of very peculiar properties. Instead of the six
freedoms, or disposables, of strain presented by a natural solid it has
only three. Change of shape of the whole can only take place in virtue
of rotation of the constituent parts relatively to any one chosen row
of them, and the plane through it and another chosen row.
§ 31. Suppose first the solids to be not only perfectly smooth but
perfectly frictionless. Let the assemblage be subjected to equal
positive or negative pressure inwards all around its boundary. Every
position of minimum, minimax, or maximum volume will be a position of
equilibrium. If the pressure is positive the equilibrium will be stable
if, and unstable unless, the volume is a minimum. If the pressure
is negative the equilibrium will be stable if, and unstable unless,
the volume is a maximum. Configurations of minimax volume will be
essentially unstable.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account