The Molecular Tactics of a CrystalKelvin, William Thomson, Baron
Science
The Molecular Tactics of a Crystal
Kelvin, William Thomson, Baron
Crystallography, Mathematical
§ 32. Consider now the assemblage of § 31 in a position of stable
equilibrium under the influence of a given constant uniform pressure
inwards all round its boundary. It will have rigidity in simple
proportion to the amount of this pressure. If now by the superposition
of non-uniform pressure at the boundary, for example equal and opposite
pressures on two sides of the assemblage, a finite change of shape is
produced: the whole assemblage essentially swells in bulk. This is the
‘dilatancy’ which Osborne Reynolds has described[9] in an exceedingly
interesting manner with reference to a sack of wheat or sand, or an
india-rubber bag tightly filled with sand or even small shot. Consider,
for example, a sack of wheat filled quite full and standing up open. It
is limp and flexible. Now shake it down well, fill it quite full, shake
again, so as to get as much into it as possible, and tie the mouth very
tightly close. The sack becomes almost as stiff as a log of wood of
the same shape. Open the mouth partially, and it becomes again limp,
especially in the upper parts of the bag. In Reynolds’ observations on
india-rubber bags of small shot his ‘dilatancy’ depends, essentially
and wholly, on breaches of some of the contacts which exist between the
molecules in their configuration of minimum volume: and it is possible
that in all his cases the dilatations which he observed are _chiefly_,
if not wholly, due to such breaches of contact.
But it is possible, it almost seems probable, that in bags or boxes
of sand or powder, of some kinds of smooth rounded bodies of any
shape, not spherical or ellipsoidal, subjected persistently to unequal
pressures in different directions, and well shaken, stable positions
of equilibrium are found with almost all the particles each touched by
twelve others.
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