The Molecular Tactics of a CrystalKelvin, William Thomson, Baron
Science
The Molecular Tactics of a Crystal
Kelvin, William Thomson, Baron
Crystallography, Mathematical
found that the stratum was visibly thicker in those crystals which
showed red colour than in those which showed blue. He concluded that
‘the seat of the coloration is certainly a thin twinned stratum’ (that
is to say, a homogeneous portion of crystal between a twinning and a
counter-twinning), and found that ‘a single twin-plane does not show
anything of the kind.’
§ 45. A year or two later Lord Rayleigh entered on the subject with
an exhaustive mathematical investigation of the reflection of light at
a twin-plane of a crystal (_Philosophical Magazine_, September, 1888),
by the application of which, in a second paper ‘On the remarkable
phenomenon of Crystalline Reflection described by Prof. Stokes,’
published in the same number of the _Philosophical Magazine_, he gave
what seems certainly the true explanation of the results of Sir George
Stokes’ experimental analysis of these beautiful phenomena. He came
very decidedly to the conclusion that the selective quality of the
iridescent portion of the crystal, in virtue of which it reflects
almost totally light nearly of one particular wave-length for one
particular direction of incidence (on which the brilliance of the
coloration depends), cannot be due to merely a single twin-stratum,
but that it essentially is due to a considerable number of parallel
twin-strata at nearly equal distances. The light reflected by this
complex stratum is, for any particular direction of incident and
reflected ray, chiefly that of which the wave-length is equal to twice
the length of the period of the twinning and counter-twinning, on a
line drawn through the stratum in the direction of either the incident
or the reflected ray.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account