The Molecular Tactics of a CrystalKelvin, William Thomson, Baron
Science
The Molecular Tactics of a Crystal
Kelvin, William Thomson, Baron
Crystallography, Mathematical
§ 43. In the second place, I must tell you that many of the crystals
produced from the watery solution by the ordinary process of slow
evaporation and crystallization, show twinnings and counter-twinnings
at irregular intervals in the otherwise homogeneous crystal on either
one or both sides of the main central twin-plane, which henceforth,
for brevity, I shall call (adopting the hypothesis already explained,
which seems to me undoubtedly true) the ‘initial plane.’ Each twinning
is followed, I believe, by a counter-twinning at a very short distance
from it; at all events Lord Rayleigh’s observations[14] prove that the
whole number of twinnings and counter-twinnings in a thin disturbed
stratum of the crystal on one side of the main central twin-plane
is generally, perhaps always, even; so that, except through some
comparatively very small part or parts of the whole thickness, the
crystal on either side of the middle or initial plane is homogeneous.
This is exactly the generally regular growth which I have described
to you (§ 39) as interrupted occasionally or accidentally by some
unexplained disturbing cause, but with an essential bias to the
homogeneous continuance of the more easy or natural one of the two
configurations.
§ 44. I have now great pleasure in showing you a most interesting
collection of the iridescent crystals of chlorate of potash, each
carefully mounted for preservation between two glass plates, which have
been kindly lent to us for this evening by Mr. Madan. In March, 1854,
Dr. W. Bird Herapath sent to Prof. Stokes some crystals of chlorate
of potash showing the brilliant and beautiful colours you now see,
and, thirty years later, Prof. E. J. Mills recalled his attention to
the subject by sending him ‘a fine collection of splendidly coloured
crystals of chlorate of potash of considerable size, several of the
plates having an area of a square inch or more, and all of them
being thick enough to handle without difficulty.’ The consequence
was that Stokes made a searching examination into the character of
the phenomenon, and gave the short, but splendidly interesting,
communication to the Royal Society of which I have already told you.
The existence of these beautifully coloured crystals had been well
known to chemical manufacturers for a long time, but it does not appear
that any mention of them was to be found in any scientific journal or
treatise prior to Stokes’ paper of 1885. He found that the colour was
due to twinnings and counter-twinnings in a very thin disturbed stratum
of the crystal showing itself by a very fine line, dark or glistening,
according to the direction of the incident light when a transverse
section of the plate of crystal was examined in a microscope. By
comparison with a spore of lycopodium he estimated that the breadth
of this line, and therefore the thickness of the disturbed stratum of
the crystal, ranged somewhere about the one-thousandth of an inch. He
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