The Molecular Tactics of a CrystalKelvin, William Thomson, Baron
Science
The Molecular Tactics of a Crystal
Kelvin, William Thomson, Baron
Crystallography, Mathematical
§ 47. And now I have sadly taxed your patience: and I fear I have
exhausted it and not exhausted my subject! I feel I have not got
halfway through what I hoped I might be able to put before you this
evening regarding the molecular structure of crystals. I particularly
desired to speak to you of quartz crystal with its ternary symmetry
and its chirality[15]; and to have told you of the etching[16] by
hydrofluoric acid which, as it were, commences to unbuild the crystal
by taking away molecule after molecule, but not in the reverse order of
the primary up-building; and which thus reveals differences of tactics
in the alternate faces of the six-sided pyramid which terminates at
either end, sometimes at both ends, the six-sided prism constituting
generally the main bulk of the crystal. I must confine myself to giving
you a geometrical symbol for the ternary symmetry of the prism and its
terminal pyramid.
[Illustration: FIG. 15.]
§ 48. Make an equilateral equiangular hexagonal prism, with
its diagonal from edge to edge ninety-five hundredths[17] of its
length. Place a number of these close together, so as to make up
a hexagonal plane layer with its sides perpendicular to the sides
of the constituent hexagonal prisms: see Fig. 15 and imagine the
semicircles replaced by their diameters. You see in each side of the
hexagonal assemblage, edges of the constituent prisms, and you see
at each corner of the assemblage a face (not an edge) of _one_ of
the constituent prisms. Build up a hexagonal prismatic assemblage
by placing layer after layer over it with the constituent prisms of
each layer vertically over those in the layer below; and finish the
assemblage with a six-sided pyramid by building upon the upper end
of the prism, layer after layer of diminishing hexagonal groups,
each less by one circumferential row than the layer below it. You
thus have a crystal of precisely the shape of a symmetrical specimen
of rock crystal, with the faces of its terminal pyramid inclined at
38° 13′ to the faces of the prism from which they spring. But the
assemblage thus constituted has ‘senary’ (or six-rayed symmetry). To
reduce this to ternary symmetry, cut a groove through the middle of
each alternate face of the prismatic molecule, making this groove
in the first place parallel to the edges: and add a corresponding
projection, or fillet, to the middles of the other three faces, so
that two of the cylinders similarly oriented would fit together, with
the projecting fillet on one side of one of them entering the groove
in the anti-corresponding side of the other. The prismatic portion
of the assemblage thus formed shows (see Fig. 15), on its alternate
edges, faces of molecules with projections and faces of molecules with
grooves; and shows only orientational differences between alternate
faces, whether of the pyramid or of the prism. Having gone only so far
from ‘senary’ symmetry, we have exactly the triple, or three-pair,
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account