The Molecular Tactics of a CrystalKelvin, William Thomson, Baron
Science
The Molecular Tactics of a Crystal
Kelvin, William Thomson, Baron
Crystallography, Mathematical
anti-symmetry required for the piezo-electricity of quartz investigated
so admirably by the brothers Curie[18], who found that a thin plate of
quartz crystal cut from any position perpendicular to a pair of faces
of a symmetrical crystal, becomes positively electrified on one side
and negatively on the other when pulled in a direction perpendicular
to those faces. But this assemblage has not the chiral piezo-electric
quality discovered theoretically by Voigt[19], and experimentally in
quartz and in tourmaline by himself and Riecke[20], nor the well-known
optic chirality of quartz.
[Illustration: FIG. 16.]
[Illustration: FIG. 17.]
§ 49. Change now the directions of the grooves and fillets to either of
the oblique configurations shown in Fig. 16, which I call right-handed,
because the directions of the projections are tangential to the threads
of a three-thread right-handed screw, and Fig. 17 (left-handed). The
prisms with their grooves and fillets will still all fit together if
they are all right-handed, or all left-handed.
[Illustration: FIG. 18.]
Fig. 18 shows the upper side of a hexagonal layer of an assemblage
thus composed of the right-handed molecule of Fig. 16. Fig. 15
unchanged, still represents a horizontal section through the centres
of the molecules. A prism built up of such layers, and finished at
each end with a pyramid according to the rule of § 48, has all the
qualities of ternary chiral symmetry required for the piezo-electricity
of quartz; for the orientational differences of the alternate pairs
of prismatic faces; for the absolute difference between the alternate
pairs of faces of each pyramid which are shown in the etching by
hydrofluoric acid; for the merely orientational difference between
the parallel faces of the two pyramids; and for the well-known
chiro-optic[21] property of quartz. Look at two contiguous faces _A_,
_B_ of our geometrical model quartz crystal now before you, with its
axis vertical. You will see a difference between them: turn it upside
down; _B_ will be undistinguishable from what _A_ was, and _A_ will be
undistinguishable from what _B_ was. Look at the two terminal pyramids,
and you will find that the face above _A_ and the face below _B_ are
identical in quality, and that they differ from the face above _B_
and below _A_. This model is composed of the right-handed constituent
molecules shown in Fig. 16. It is so placed before you that the edge of
the prismatic part of the assemblage nearest to you shows you filleted
faces of the prismatic molecules. You see two pyramidal faces; the one
to your right hand, over _B_, presents complicated projections and
hollows at the corners of the constituent molecules; and the pyramidal
face next your left hand, over _A_, presents their unmodified corners.
But it will be the face next your left hand which will present the
complex bristling corners, and the face next your right hand that
will present the simple corners, if, for the model before you, you
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