The Molecular Tactics of a CrystalKelvin, William Thomson, Baron
Science
The Molecular Tactics of a Crystal
Kelvin, William Thomson, Baron
Crystallography, Mathematical
§ 11. In Figs. 5 and 6 you see two assemblages, each of twelve equal
and similar molecules in a plane. Fig. 5, in which the molecules are
all same-ways oriented, is one homogeneous assemblage of twenty-four
molecules. Fig. 6, in which in one set of rows the molecules are
alternately oriented two different ways, may either be regarded as
two homogeneous assemblages, each of twelve single molecules; or one
homogeneous assemblage of twelve pairs of those single molecules.
[Illustration: FIG. 5.]
§ 12. I must now call your attention to a purely geometrical
question[3] of vital interest with respect to homogeneous assemblages
in general, and particularly the homogeneous assemblage of molecules
constituting a crystal:--_what can we take as ‘the’ boundary or ‘a’
boundary enclosing each molecule with whatever portion of space around
it we are at liberty to choose for_ _it, and separating it from
neighbours and their portions of space given to them in homogeneous
fairness?_
[Illustration: FIG. 6.]
§ 13. If we had only mathematical points to consider we should be at
liberty to choose the simple obvious partitioning by three sets of
parallel planes. Even this may be done in an infinite number of ways,
thus:--Beginning with any point _P_ of the assemblage, choose any other
three points _A_, _B_, _C_, far or near, provided only that they are
not in one plane with _P_, and that there is no other point of the
assemblage in the lines _PA_, _PB_, _PC_, or within the volume of the
parallelepiped of which these lines are conterminous edges, or within
the areas of any of the faces of this parallelepiped. There will be
points of the assemblage at each of the corners of this parallelepiped
and at all the corners of the parallelepipeds equal and similar to
it which we find by drawing sets of equi-distant planes parallel to
its three pairs of faces. (A diagram is unnecessary.) Every point of
the assemblage is thus at the intersection of three planes, which is
also the point of meeting of eight neighbouring parallelepipeds. Shift
now any one of the points of the assemblage to a position within the
volume of any one of the eight parallelepipeds, and give equal parallel
motions to all the other points of the assemblage. Thus we have every
point in a parallelepipedal cell of its own, and all the points of the
assemblage are similarly placed in their cells, which are themselves
equal and similar.
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