The Monist, Vol. 3, 1892-1893 : $b A quarterly magazineVarious
Philosophy
The Monist, Vol. 3, 1892-1893 : $b A quarterly magazine
Various
Philosophy -- Periodicals
The truth is that several different kinds of dissociation have to be
distinguished. In the first place, there is the dissociation of a
chemical molecule to form chemical molecules under the regular action of
chemical laws. This may be a double decomposition, as when iodhydric acid
is dissociated, according to the formula
HI + HI = HH + II;
or, it may be a simple decomposition, as when pentachloride of phosphorus
is dissociated according to the formula
PCl₅ = PCl₃ + ClCl.
All these dissociations require, according to the laws of
thermochemistry, an elevated temperature. In the second place, there is
the dissociation of a physically polymerous molecule, that is, of several
chemical molecules joined by physical attractions. This I am inclined to
suppose is a common concomitant of the heating of solids and liquids;
for in these bodies there is no increase of compressibility with the
temperature at all comparable with the increase of the expansibility.
But, in the third place, there is the dissociation with which we are now
concerned, which must be supposed to be a throwing off of unsaturated
sub-molecules or atoms from the molecule. The molecule may, as I have
said, be roughly likened to a solar system. As such, molecules are able
to produce perturbations of one another’s internal motions; and in this
way a planet, i. e. a sub-molecule, will occasionally get thrown off and
wander about by itself, till it finds another unsaturated sub-molecule
with which it can unite. Such dissociation by perturbation will naturally
be favored by the proximity of the molecules to one another.
Public-domain text, read in full here on John Shaqi.
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