The Mysterious Box: Nuclear Science and ArtKeisch, Bernard
Science
The Mysterious Box: Nuclear Science and Art
Keisch, Bernard
Painting -- Radiography -- Juvenile literature
Over the next few weeks quite a few things happened to the boys and
their paintings. Three of them were discarded right away because they
were immediately recognized as being copies of no value. Two were
relatively modern paintings with the signature Alfred Sisley; if
genuine, they were less than 100 years old. The remaining four appeared
to be very old paintings. Two of them seemed to correspond to paintings
that disappeared during the Second World War. Photographs and X rays
were taken and sent to the museum in Holland, which had owned the
missing pictures, so that they could make a preliminary examination.
[Illustration: uncaptioned]
Radioactivity of Lead-210
Lead-210 decaying with a half-life of 22 years. When no radium is
present there is almost none left after 6 half-lives or 132 years.
Radioactivity of Radium-226
Over the same period of time, a small amount of radium decays very
little because its half-life is about 1600 years.
Radioactivity of Radium 226
Radioactivity of Lead-210
But when lead-210 decays in the presence of radium-226, the
radioactivity of the lead-210 only decreases until it is equal to
the radioactivity of the radium.
That left two that could have been old but whose origins were unknown. A
series of simple chemical tests were begun on these and the boys watched
experts take very small samples of paint for examination under the
microscope. After several months a list of the pigments present in the
paintings was prepared. All the pigments found were typical of old
paintings and the ordinary examinations and tests couldn’t prove whether
the works were old or not. Finally, it was decided that the only way to
tell if these paintings were truly old was to apply the test that Dad
had described to the boys.
The boys watched a painting restorer remove samples of nearly white
paint right at the edge of the paintings. He worked carefully, using a
very sharp scalpel and a stereo-binocular microscope, through which
objects appeared to be sixty times larger than they really were. The
sample of paint weighed approximately twenty-thousandths of a gram. The
boys and their father took the samples to a radiochemical laboratory
where they watched a radiochemist do the required analysis for lead-210
and radium in the samples.
First the chemist dissolved the paint in acetic acid. This removed the
lead white from the oil and from the small amounts of other pigments in
the paint. The solutions were then heated and stirred with a silver disc
hanging in the liquid. After several hours the disc still looked clean,
but the chemist said that a radioactive element, polonium-210, was now
plated onto the silver. Polonium-210 is a member of the uranium series
following the lead-210, and a measurement of its radioactivity would be
an accurate measurement of the radioactivity of lead-210.
Public-domain text, read in full here on John Shaqi.
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