The Natural History of ClaySearle, Alfred B. (Alfred Broadhead)
Science
The Natural History of Clay
Searle, Alfred B. (Alfred Broadhead)
Clay
So far as clays are concerned, their plasticity appears to be connected
with the presence of combined water as well as of mechanically mixed
water, for if either of these are removed, plasticity--both actual and
potential--is destroyed. The part played by water is not, however,
completely known, for the many theories which have been advanced only
cover some of the conditions and facts.
A number of observers agree that the molecular constitution of clay is
peculiar and that it is to this that plasticity is due. Yet the curious
fact that the purest clays--the kaolins--are remarkably deficient in
plasticity shows that molecular constitution is not, alone, sufficient.
Others hold that the remarkably small size of clay particles enables
them to pack together more closely than do particles of other materials
and to retain around them a film of water which acts partly as a
lubricant, facilitating the change of shape of the mass when under
pressure, and partly as an adhesive, causing the particles to adhere to
each other when the pressure is removed.
Zschokke has laid much emphasis on the importance of molecular
attraction between clay and water as a cause of plasticity, and has
suggested that the absorption of the water effects a change in the
surfaces of the clay particles, giving them a gelatinous nature and
enabling them to change their form and yet keep in close contact.
The fact that mica, fluorspar and quartz, when in a sufficiently finely
divided state, are also slightly plastic, appears to be opposed to the
molecular constitution theory. Smallness of grain undoubtedly has an
influence on the plasticity of clay, coarse-grained clays being notably
less plastic than others.
Daubrée pointed out that felspar, when ground with water, develops
plasticity to a small extent, and Olschewsky carried this observation
further and has suggested that clays owe their plasticity to prolonged
contact with water during their removal from their place of formation
and previous to or during their deposition. A further confirmation of
this theory is due to Mellor (3) who showed that on heating china clay
with water under very considerable pressure its plasticity was increased
and that felspar and some other non-plastic materials developed
plasticity under these conditions.
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