The Natural History of ClaySearle, Alfred B. (Alfred Broadhead)
Science
The Natural History of Clay
Searle, Alfred B. (Alfred Broadhead)
Clay
Johnson and Blake (21) supposed that plasticity is due to the clay being
composed of extremely minute plates 'bunched together,' a view which was
also held by Biedermann and Herzfield, Le Chatelier and others.
Olschewsky enlarged this theory by suggesting that the plasticity of
certain clays is dependent on the large surface and the interlocking of
irregular particles with the plates just mentioned. These theories of
interlocking are, however, incomplete, because the tensile strength of
clays should accurately represent the plasticity if interlocking were
the sole cause. Zschokke has shown that tensile strength is only one
factor which must be determined in any attempt to measure plasticity.
E. H. L. Schwarz (35) has suggested that many clays are composed of
small globular masses of plates so arranged as to form an open network
(fig. 4) which is sufficiently strong not to be destroyed by pressure.
In the presence of water and much rubbing the plates are separated and
are made to lie flat on each other, thereby giving a plastic and
impermeable mass. If this is really the case it would explain the
porosity and large surface of some clays and might account for their
adsorptive power.
[Illustration: Fig. 4. Illustrating the structure of a 'clay crumb.'
(_After Schwarz._)]
A theory which was first promulgated in 1850 by Way (4), but which has
only received detailed attention during the last few years, attributes
plasticity to the presence of colloid substances in clay or to the fact
that clay particles possess physical characters analogous to those of
glue and other colloids. These colloid substances have a submicroscopic
or micellian structure; they are web-like, porous and absorb water
eagerly. This water may be removed by drying, only to be re-absorbed on
cooling, but if the heating temperature is excessive the structure of
the colloids is destroyed. This colloid theory explains many of the
facts noted by earlier investigators such as Aron, Bischof, Seger,
Olschewsky, etc., but it is not entirely satisfactory, though Rohland
(5)--to whom the present prominence of this theory in Europe is largely
due--persistently maintains the contrary. One great objection is the
fact that no characteristic _inorganic_ colloid substance has been
isolated from pure clay. It is possible that some of the so-called
'colloidal' properties of clay may be due to the smallness of its
particles and to their great porosity, as suggested by Olschewsky.
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