The Natural History of ClaySearle, Alfred B. (Alfred Broadhead)
Science
The Natural History of Clay
Searle, Alfred B. (Alfred Broadhead)
Clay
Despite the present impossibility of producing a plastic material from
artificially prepared colloidal hydro-alumino-silicates of the same
ultimate composition as clay, and the fact that the addition of
colloidal substances does not necessarily increase the true plasticity
of clay, it cannot be denied that the presence of colloids has an
important influence on it. The addition of starches, glue, gums and
similar substances whilst apparently increasing the plasticity of clay
does not do so in reality. The addition of 1 per cent. of tannin, on the
contrary, has been found by Ries (6) to increase both plasticity and
binding power.
Plasticity appears to be composed of a number of characteristics so that
it is scarcely likely that any single cause can be assigned to it. On
the contrary, a study of the binding power, tensile strength,
extensibility, adsorption, texture and molecular constitution of clays
suggests very strongly that all these properties are involved in the
production of plasticity and that it is due to the chemical as well as
the physical nature of clay. No clay is entirely colloidal--or it would
be elastic and not plastic--but all appear to contain both colloidal and
non-colloidal (including plate-like) particles, and it is not improbable
that materials in both these states are required, the colloidal matter
acting as a cement. Ries (6) has, in fact, pointed out that colloids
alone lack cohesiveness and solidity, and a fine mineral aggregate is
necessary to change them into a plastic mass resembling clay. The
relative proportions of the colloidal material and the sizes of the
non-plastic grains will exercise an important influence on all the
physical characteristics mentioned above, and therefore on the
plasticity.
The manner in which slightly plastic clays become highly plastic in
nature is by no means certainly known. It has long been understood that
the increase of plasticity is due to changes undergone by the clay
during transportation. The most illuminating suggestion is that made by
Acheson in 1902, who concluded that it is due to impurities in the water
used in transporting the clay or remaining in contact with it during and
after its deposition. These impurities may be considered as derived from
the washings of forests, and after many experiments with plant extracts
Acheson believed the most important substance in this connection to be
tannin or gallo-tannic acid, a dilute solution of which he found
increased the plasticity of china clay by 300 per cent. From this he
further argued that the use of chopped straw by the Israelites in Egypt
in the manufacture of bricks was unconsciously based on the tannin
content of the straw increasing the plasticity of the material.
[Illustration: Fig. 5. Chart showing rates of drying. (_After
Bleininger._)]
Beadle has stated that 2 per cent. of dissolved cellulose will increase
the plasticity of china clay and make it equal to that of ordinary
clay.
Public-domain text, read in full here on John Shaqi.
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