The Natural History of ClaySearle, Alfred B. (Alfred Broadhead)
Science
The Natural History of Clay
Searle, Alfred B. (Alfred Broadhead)
Clay
The _shrinkage_ which all clays undergo on drying and when heated is
another important characteristic. It is due to the fact that as water is
removed the solid particles approach closer to each other, the volume of
the whole mass being thereby reduced. In a wet piece of clay each
particle is surrounded by a film of water, the thickness of which
depends on the nature of the clay. As this water evaporates from the
surface of the clay its place is taken by water from the interior which
rises to the surface by capillary attraction. So long as there is any
water between the particles of clay there will be shrinkage when this
water is removed, but a stage is eventually reached when the particles
of clay are in contact with each other and no more shrinkage can occur.
That this cessation of shrinkage may take place before all the water has
been removed from the clay is easily understood when it is remembered
that whilst the clay particles may be in contact, yet there are still
places (pores) where the contact is incomplete, and in these pores water
may be retained. The amount of shrinkage clays undergo on drying depends
partly on the proportion of water added to them and partly on the sizes
of the different particles of clay, sand, etc. present. An average
reduction in volume of 12 to 38 per cent. may be regarded as normal, but
coarse loams may shrink only 1 per cent. and very finely ground, highly
plastic ball clays may shrink as much as 50 per cent., though this is
unusual.
As all coagulated colloids, which have absorbed water, shrink on drying,
this behaviour of clay appears to confirm the view as to its partially
colloidal nature held by some investigators.
When a piece of dry clay is heated sufficiently a further shrinkage
(technically known as _kiln shrinkage_) occurs. This begins somewhat
below a red heat and increases in rough proportion to the temperature
and the duration of the heating. Prolonged heating at a lower
temperature will effect the same amount of shrinkage as a short exposure
to a higher temperature, but though the greater part of the shrinkage
occurs in a comparatively short time, continued heating will be
accompanied by a further reduction in volume.
This is due to the fact that clays have no definite melting point, but
undergo partial fusion at all temperatures above 950° C. or, in some
cases, at even lower ones. As a portion of the material fuses, it fills
up the pores in the mass and attacks the unfused material, this process
being continued until either the heating is stopped or the whole
material is reduced to a viscous slag.
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