The Natural History of ClaySearle, Alfred B. (Alfred Broadhead)
Science
The Natural History of Clay
Searle, Alfred B. (Alfred Broadhead)
Clay
The reduction in the volume of commercial articles made of clay and
placed in kilns varies greatly. With bricks, terra-cotta and pottery it
must not, usually, exceed 40 per cent. or the warping and cracking which
occur will be so great as to make the articles useless. The fineness of
the particles exercises an important influence on the kiln shrinkage of
a clay, and the latter is frequently reduced in commercial clayworking
by adding burned clay ground to a coarse powder to the plastic clay
before it is used. Sand is sometimes added for the same purpose, though
its more frequent use is to reduce the shrinkage in drying.
Quartz and other forms of free silica expand on heating, so that clays
containing them in large quantities shrink very slightly or may even
expand.
As clays shrink equally in all directions it is usual to state the
contraction in linear instead of volume form. Thus instead of stating
that a certain clay when moulded into bricks, dried and burned, shrinks
18 per cent. by volume, it is customary to state that it shrinks 3/4 in.
per (linear) foot. For many purposes, it is sufficient to regard the
linear shrinkage as one-third the volume-shrinkage, but this is not
strictly accurate.
The _fusibility_ of clays is a characteristic which has been very
imperfectly studied. Most clayworkers and investigators employ the term
'fusibility' in a special sense which is apt to be misleading. Owing to
the extremely high temperatures to which refractory clays can be heated
without even losing their shape, it is almost impossible to fuse them
completely. In addition to this, clays are not perfectly homogeneous
materials and some of their constituents melt at lower temperatures than
others. For this reason a clay may show signs of fusion at 1100° C., but
it may be heated for some hours at 1800° C. and yet not be completely
melted! Consequently no single 'fusing point' can be stated.
In practice, a suggestion made many years ago by Seger (7) is used; the
clay to be tested is made into a small tetrahedron (fig. 6), heated
slowly until it bends over and the point of the test-piece is almost on
a level with the base. The temperature at which this occurs is termed
the 'fusing point' though it really only indicates the heat-treatment
which is sufficient to soften the material sufficiently to cause it to
bend in the manner described. In spite of the apparent crudeness of the
test this 'softening point' appears to be fairly constant for most
refractory clays.
Public-domain text, read in full here on John Shaqi.
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